Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
Catalytic reduction of CO2 and biomass derivatives is of great current interest from a sustainable chemistry perspective. Here, the authors report a manganese pincer complex able to reduce under mild conditions carboxylic acids, carbonates and even carbon dioxide using pinacolborane as reducing agen...
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Nature Portfolio
2018
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oai:doaj.org-article:9dda0e0185c04b6fa7371661ef6b84b62021-12-02T14:39:23ZManganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups10.1038/s41467-018-06831-92041-1723https://doaj.org/article/9dda0e0185c04b6fa7371661ef6b84b62018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06831-9https://doaj.org/toc/2041-1723Catalytic reduction of CO2 and biomass derivatives is of great current interest from a sustainable chemistry perspective. Here, the authors report a manganese pincer complex able to reduce under mild conditions carboxylic acids, carbonates and even carbon dioxide using pinacolborane as reducing agent.Christina ErkenAkash KaithalSuman SenThomas WeyhermüllerMarkus HölscherChristophe WerléWalter LeitnerNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018) |
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Science Q Christina Erken Akash Kaithal Suman Sen Thomas Weyhermüller Markus Hölscher Christophe Werlé Walter Leitner Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
description |
Catalytic reduction of CO2 and biomass derivatives is of great current interest from a sustainable chemistry perspective. Here, the authors report a manganese pincer complex able to reduce under mild conditions carboxylic acids, carbonates and even carbon dioxide using pinacolborane as reducing agent. |
format |
article |
author |
Christina Erken Akash Kaithal Suman Sen Thomas Weyhermüller Markus Hölscher Christophe Werlé Walter Leitner |
author_facet |
Christina Erken Akash Kaithal Suman Sen Thomas Weyhermüller Markus Hölscher Christophe Werlé Walter Leitner |
author_sort |
Christina Erken |
title |
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
title_short |
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
title_full |
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
title_fullStr |
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
title_full_unstemmed |
Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
title_sort |
manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/9dda0e0185c04b6fa7371661ef6b84b6 |
work_keys_str_mv |
AT christinaerken manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT akashkaithal manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT sumansen manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT thomasweyhermuller manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT markusholscher manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT christophewerle manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups AT walterleitner manganesecatalyzedhydroborationofcarbondioxideandotherchallengingcarbonylgroups |
_version_ |
1718390671280177152 |