Frustrated flexibility in metal-organic frameworks

Responsiveness in metal-organic frameworks involving amorphous phases remains poorly understood. Here, the authors demonstrate MOFs that reversibly switch between well-defined crystalline and structurally degenerate amorphous states mediated by competing intra-framework forces.

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Detalles Bibliográficos
Autores principales:	Roman Pallach, Julian Keupp, Kai Terlinden, Louis Frentzel-Beyme, Marvin Kloß, Andrea Machalica, Julia Kotschy, Suresh K. Vasa, Philip A. Chater, Christian Sternemann, Michael T. Wharmby, Rasmus Linser, Rochus Schmid, Sebastian Henke
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/9e050c6f8e264f0088d54bd489bd6dcb
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spelling	oai:doaj.org-article:9e050c6f8e264f0088d54bd489bd6dcb2021-12-02T14:34:13ZFrustrated flexibility in metal-organic frameworks10.1038/s41467-021-24188-42041-1723https://doaj.org/article/9e050c6f8e264f0088d54bd489bd6dcb2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24188-4https://doaj.org/toc/2041-1723Responsiveness in metal-organic frameworks involving amorphous phases remains poorly understood. Here, the authors demonstrate MOFs that reversibly switch between well-defined crystalline and structurally degenerate amorphous states mediated by competing intra-framework forces.Roman PallachJulian KeuppKai TerlindenLouis Frentzel-BeymeMarvin KloßAndrea MachalicaJulia KotschySuresh K. VasaPhilip A. ChaterChristian SternemannMichael T. WharmbyRasmus LinserRochus SchmidSebastian HenkeNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-12 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Roman Pallach Julian Keupp Kai Terlinden Louis Frentzel-Beyme Marvin Kloß Andrea Machalica Julia Kotschy Suresh K. Vasa Philip A. Chater Christian Sternemann Michael T. Wharmby Rasmus Linser Rochus Schmid Sebastian Henke Frustrated flexibility in metal-organic frameworks
description	Responsiveness in metal-organic frameworks involving amorphous phases remains poorly understood. Here, the authors demonstrate MOFs that reversibly switch between well-defined crystalline and structurally degenerate amorphous states mediated by competing intra-framework forces.
format	article
author	Roman Pallach Julian Keupp Kai Terlinden Louis Frentzel-Beyme Marvin Kloß Andrea Machalica Julia Kotschy Suresh K. Vasa Philip A. Chater Christian Sternemann Michael T. Wharmby Rasmus Linser Rochus Schmid Sebastian Henke
author_facet	Roman Pallach Julian Keupp Kai Terlinden Louis Frentzel-Beyme Marvin Kloß Andrea Machalica Julia Kotschy Suresh K. Vasa Philip A. Chater Christian Sternemann Michael T. Wharmby Rasmus Linser Rochus Schmid Sebastian Henke
author_sort	Roman Pallach
title	Frustrated flexibility in metal-organic frameworks
title_short	Frustrated flexibility in metal-organic frameworks
title_full	Frustrated flexibility in metal-organic frameworks
title_fullStr	Frustrated flexibility in metal-organic frameworks
title_full_unstemmed	Frustrated flexibility in metal-organic frameworks
title_sort	frustrated flexibility in metal-organic frameworks
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/9e050c6f8e264f0088d54bd489bd6dcb
work_keys_str_mv	AT romanpallach frustratedflexibilityinmetalorganicframeworks AT juliankeupp frustratedflexibilityinmetalorganicframeworks AT kaiterlinden frustratedflexibilityinmetalorganicframeworks AT louisfrentzelbeyme frustratedflexibilityinmetalorganicframeworks AT marvinkloß frustratedflexibilityinmetalorganicframeworks AT andreamachalica frustratedflexibilityinmetalorganicframeworks AT juliakotschy frustratedflexibilityinmetalorganicframeworks AT sureshkvasa frustratedflexibilityinmetalorganicframeworks AT philipachater frustratedflexibilityinmetalorganicframeworks AT christiansternemann frustratedflexibilityinmetalorganicframeworks AT michaeltwharmby frustratedflexibilityinmetalorganicframeworks AT rasmuslinser frustratedflexibilityinmetalorganicframeworks AT rochusschmid frustratedflexibilityinmetalorganicframeworks AT sebastianhenke frustratedflexibilityinmetalorganicframeworks
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Frustrated flexibility in metal-organic frameworks

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