Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation

Perovskite-type structures LaBO3 with the compositions of LaMn1-xCoxO3 (x = 0.0, 0.3, 0.5, 0.7, and 1.0) were synthesized at 800 °C by a modified co-precipitation precursor technique for total oxidation of propylene, as a model test of the hydrocarbon oxidation reaction. Details concerning the evolu...

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Autores principales:	Teotone Inas Mariano Vaz, Sridhar Maruti Gurav, Arun Vithal Salker
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2021
Materias:	rare earth perovskites co-precipitation catalytic oxidation propylene Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/9e19519e4929490f8cc8c2582ac0a0bd
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spelling	oai:doaj.org-article:9e19519e4929490f8cc8c2582ac0a0bd2021-12-02T18:02:39ZInfluence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation1411-94202460-157810.22146/ijc.65766https://doaj.org/article/9e19519e4929490f8cc8c2582ac0a0bd2021-09-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/65766https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578Perovskite-type structures LaBO3 with the compositions of LaMn1-xCoxO3 (x = 0.0, 0.3, 0.5, 0.7, and 1.0) were synthesized at 800 °C by a modified co-precipitation precursor technique for total oxidation of propylene, as a model test of the hydrocarbon oxidation reaction. Details concerning the evolution of the crystal structure, morphology, and crystallite size were performed by X-ray diffraction (XRD), Thermo Gravimetry Analysis (TGA)/Differential Scanning Calorimetry (DSC), Fourier Transform Infra-Red (FTIR), Atomic Absorption Spectroscopy (AAS), Scanning Electron Microscopy (SEM), and Electron Spin Resonance (ESR) techniques. All compositions were identified to be single-phase and are indexed to rhombohedral structures. TG/DSC technique evidenced a temperature of 330 °C needed for the precursor as the start point and 800 °C completion for perovskite phase formation. Slight distortion in XRD diffraction peaks was observed on substituting manganese with cobalt in B-site, and new peaks emerged. An attempt has been made to understand the effect of the B-site substitution of Co3+ ions in the lattice of LaMnO3 and their influence on catalytic total propylene oxidation efficiency. These compounds show a considerable increase in the activity of propylene oxidation to carbon dioxide and water and could be explored for hydrocarbon pollution control.Teotone Inas Mariano VazSridhar Maruti GuravArun Vithal SalkerDepartment of Chemistry, Universitas Gadjah Madaarticlerare earth perovskitesco-precipitationcatalytic oxidationpropyleneChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 5, Pp 1244-1251 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	rare earth perovskites co-precipitation catalytic oxidation propylene Chemistry QD1-999
spellingShingle	rare earth perovskites co-precipitation catalytic oxidation propylene Chemistry QD1-999 Teotone Inas Mariano Vaz Sridhar Maruti Gurav Arun Vithal Salker Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
description	Perovskite-type structures LaBO3 with the compositions of LaMn1-xCoxO3 (x = 0.0, 0.3, 0.5, 0.7, and 1.0) were synthesized at 800 °C by a modified co-precipitation precursor technique for total oxidation of propylene, as a model test of the hydrocarbon oxidation reaction. Details concerning the evolution of the crystal structure, morphology, and crystallite size were performed by X-ray diffraction (XRD), Thermo Gravimetry Analysis (TGA)/Differential Scanning Calorimetry (DSC), Fourier Transform Infra-Red (FTIR), Atomic Absorption Spectroscopy (AAS), Scanning Electron Microscopy (SEM), and Electron Spin Resonance (ESR) techniques. All compositions were identified to be single-phase and are indexed to rhombohedral structures. TG/DSC technique evidenced a temperature of 330 °C needed for the precursor as the start point and 800 °C completion for perovskite phase formation. Slight distortion in XRD diffraction peaks was observed on substituting manganese with cobalt in B-site, and new peaks emerged. An attempt has been made to understand the effect of the B-site substitution of Co3+ ions in the lattice of LaMnO3 and their influence on catalytic total propylene oxidation efficiency. These compounds show a considerable increase in the activity of propylene oxidation to carbon dioxide and water and could be explored for hydrocarbon pollution control.
format	article
author	Teotone Inas Mariano Vaz Sridhar Maruti Gurav Arun Vithal Salker
author_facet	Teotone Inas Mariano Vaz Sridhar Maruti Gurav Arun Vithal Salker
author_sort	Teotone Inas Mariano Vaz
title	Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
title_short	Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
title_full	Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
title_fullStr	Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
title_full_unstemmed	Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation
title_sort	influence of cobalt substitution in lamno<sub>3</sub> on catalytic propylene oxidation
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2021
url	https://doaj.org/article/9e19519e4929490f8cc8c2582ac0a0bd
work_keys_str_mv	AT teotoneinasmarianovaz influenceofcobaltsubstitutioninlamnosub3suboncatalyticpropyleneoxidation AT sridharmarutigurav influenceofcobaltsubstitutioninlamnosub3suboncatalyticpropyleneoxidation AT arunvithalsalker influenceofcobaltsubstitutioninlamnosub3suboncatalyticpropyleneoxidation
_version_	1718378884354801664

Influence of Cobalt Substitution in LaMnO<sub>3</sub> on Catalytic Propylene Oxidation

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