Semiconductor-oxide nanocomposites based on porous semiconductors

Rare-earth containing oxide nanocomposites are prepared of porous GaP and GaAs templates in a controlled fashion. The initial porous GaP and GaAs networks are replaced by GaPO4 and Ga2O3 structures, respectively, during annealing at emperatures from 500 to 900 o C. The impregnation of Eu and Er...

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Autores principales: Hmelevschi, Leonid, Tighineanu, Ion, Ursachi, Veaceslav, Dolgaleva, Ksenia, Boyd, Robert W.
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Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2007
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Acceso en línea:https://doaj.org/article/9e21e8ea12564bc9ac41a109aa76f0c9
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spelling oai:doaj.org-article:9e21e8ea12564bc9ac41a109aa76f0c92021-11-21T12:07:53ZSemiconductor-oxide nanocomposites based on porous semiconductors2537-63651810-648Xhttps://doaj.org/article/9e21e8ea12564bc9ac41a109aa76f0c92007-05-01T00:00:00Zhttps://mjps.nanotech.md/archive/2007/article/3703https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Rare-earth containing oxide nanocomposites are prepared of porous GaP and GaAs templates in a controlled fashion. The initial porous GaP and GaAs networks are replaced by GaPO4 and Ga2O3 structures, respectively, during annealing at emperatures from 500 to 900 o C. The impregnation of Eu and Er lanthanides from EuCl3:C2H5OH and ErCl3:C2H5OH solutions results in the formation of lanthanide containing oxide microcrystals finely dispersed into the native oxide matrix. These oxide phases are found to be EuPO4 and ErPO4 in composites obtained on GaP templates, and EuAsO4 and ErAsO4 in composites prepared on GaAs templates. 4f-4f intrashell transitions in Eu3 and Er3 ions assure strong red and green emission from these nanophases. Hmelevschi, LeonidTighineanu, IonUrsachi, VeaceslavDolgaleva, KseniaBoyd, Robert W.D.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 6, Iss 2, Pp 142-147 (2007)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Hmelevschi, Leonid
Tighineanu, Ion
Ursachi, Veaceslav
Dolgaleva, Ksenia
Boyd, Robert W.
Semiconductor-oxide nanocomposites based on porous semiconductors
description Rare-earth containing oxide nanocomposites are prepared of porous GaP and GaAs templates in a controlled fashion. The initial porous GaP and GaAs networks are replaced by GaPO4 and Ga2O3 structures, respectively, during annealing at emperatures from 500 to 900 o C. The impregnation of Eu and Er lanthanides from EuCl3:C2H5OH and ErCl3:C2H5OH solutions results in the formation of lanthanide containing oxide microcrystals finely dispersed into the native oxide matrix. These oxide phases are found to be EuPO4 and ErPO4 in composites obtained on GaP templates, and EuAsO4 and ErAsO4 in composites prepared on GaAs templates. 4f-4f intrashell transitions in Eu3 and Er3 ions assure strong red and green emission from these nanophases.
format article
author Hmelevschi, Leonid
Tighineanu, Ion
Ursachi, Veaceslav
Dolgaleva, Ksenia
Boyd, Robert W.
author_facet Hmelevschi, Leonid
Tighineanu, Ion
Ursachi, Veaceslav
Dolgaleva, Ksenia
Boyd, Robert W.
author_sort Hmelevschi, Leonid
title Semiconductor-oxide nanocomposites based on porous semiconductors
title_short Semiconductor-oxide nanocomposites based on porous semiconductors
title_full Semiconductor-oxide nanocomposites based on porous semiconductors
title_fullStr Semiconductor-oxide nanocomposites based on porous semiconductors
title_full_unstemmed Semiconductor-oxide nanocomposites based on porous semiconductors
title_sort semiconductor-oxide nanocomposites based on porous semiconductors
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2007
url https://doaj.org/article/9e21e8ea12564bc9ac41a109aa76f0c9
work_keys_str_mv AT hmelevschileonid semiconductoroxidenanocompositesbasedonporoussemiconductors
AT tighineanuion semiconductoroxidenanocompositesbasedonporoussemiconductors
AT ursachiveaceslav semiconductoroxidenanocompositesbasedonporoussemiconductors
AT dolgalevaksenia semiconductoroxidenanocompositesbasedonporoussemiconductors
AT boydrobertw semiconductoroxidenanocompositesbasedonporoussemiconductors
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