NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters

A new polymeric NHC carrier was synthesized by sequential supramolecular self-assembly and copper-catalyzed azide-alkyne cycloaddition (CuAAC) of amphiphilic imidazolium calix[4]arenes with octyl lipophilic fragments. Obtained polytriazole-imidazolium particles were found as monodisperse submicron p...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Vladimir Burilov, Diana Mironova, Elsa Sultanova, Ramila Garipova, Vladimir Evtugyn, Svetlana Solovieva, Igor Antipin
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	calixarene CuAAC polyNHC Pd nanoclusters Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/9e43a4ef94a442abbd681f350237131d
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:9e43a4ef94a442abbd681f350237131d
record_format	dspace
spelling	oai:doaj.org-article:9e43a4ef94a442abbd681f350237131d2021-11-25T18:27:55ZNHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters10.3390/molecules262268641420-3049https://doaj.org/article/9e43a4ef94a442abbd681f350237131d2021-11-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/22/6864https://doaj.org/toc/1420-3049A new polymeric NHC carrier was synthesized by sequential supramolecular self-assembly and copper-catalyzed azide-alkyne cycloaddition (CuAAC) of amphiphilic imidazolium calix[4]arenes with octyl lipophilic fragments. Obtained polytriazole-imidazolium particles were found as monodisperse submicron particles, with the average diameter of 236 ± 34 nm and average molecular weight of 1380 ± 96 kDa. Successful CuAAC polymerization has been proved using IR spectroscopy and high-resolution ESI mass spectrometry. Polymeric particles, as well as aggregates made from precursor macrocycles, were decorated by Pd clusters (2 nm) for further catalytic investigations. Pd nanoclusters, supported on the polymeric surface, were found highly catalytically active in the model reduction of <i>p</i>-nitrophenol, giving reaction rates an order of magnitude higher compared to literature examples. The reaction was recycled using the same catalyst five times without any loss of activity.Vladimir BurilovDiana MironovaElsa SultanovaRamila GaripovaVladimir EvtugynSvetlana SolovievaIgor AntipinMDPI AGarticlecalixareneCuAACpolyNHCPd nanoclustersOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6864, p 6864 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	calixarene CuAAC polyNHC Pd nanoclusters Organic chemistry QD241-441
spellingShingle	calixarene CuAAC polyNHC Pd nanoclusters Organic chemistry QD241-441 Vladimir Burilov Diana Mironova Elsa Sultanova Ramila Garipova Vladimir Evtugyn Svetlana Solovieva Igor Antipin NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
description	A new polymeric NHC carrier was synthesized by sequential supramolecular self-assembly and copper-catalyzed azide-alkyne cycloaddition (CuAAC) of amphiphilic imidazolium calix[4]arenes with octyl lipophilic fragments. Obtained polytriazole-imidazolium particles were found as monodisperse submicron particles, with the average diameter of 236 ± 34 nm and average molecular weight of 1380 ± 96 kDa. Successful CuAAC polymerization has been proved using IR spectroscopy and high-resolution ESI mass spectrometry. Polymeric particles, as well as aggregates made from precursor macrocycles, were decorated by Pd clusters (2 nm) for further catalytic investigations. Pd nanoclusters, supported on the polymeric surface, were found highly catalytically active in the model reduction of <i>p</i>-nitrophenol, giving reaction rates an order of magnitude higher compared to literature examples. The reaction was recycled using the same catalyst five times without any loss of activity.
format	article
author	Vladimir Burilov Diana Mironova Elsa Sultanova Ramila Garipova Vladimir Evtugyn Svetlana Solovieva Igor Antipin
author_facet	Vladimir Burilov Diana Mironova Elsa Sultanova Ramila Garipova Vladimir Evtugyn Svetlana Solovieva Igor Antipin
author_sort	Vladimir Burilov
title	NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
title_short	NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
title_full	NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
title_fullStr	NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
title_full_unstemmed	NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters
title_sort	nhc polymeric particles obtained by self-assembly and click approach of calix[4]arene amphiphiles as support for catalytically active pd nanoclusters
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9e43a4ef94a442abbd681f350237131d
work_keys_str_mv	AT vladimirburilov nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT dianamironova nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT elsasultanova nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT ramilagaripova nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT vladimirevtugyn nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT svetlanasolovieva nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters AT igorantipin nhcpolymericparticlesobtainedbyselfassemblyandclickapproachofcalix4areneamphiphilesassupportforcatalyticallyactivepdnanoclusters
_version_	1718411148137594880

NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters

Ejemplares similares