Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film

This study carried out on the effect of precursor concentration and annealed substrate temperature on the crystal structure, electronic and optical properties of ZnO thin film. An aqueous solution of Acid Nitrite was used as precursors and its concentration was varied from 0.1 M to 0.4 M. The ZnO th...

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Autores principales: Yus Rama Denny Muchtar, Teguh Firmansyah, Adhitya Trenggono, Danu Wijaya, Ganesha Antarnusa, Andri Suherman
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Publicado: University of Brawijaya 2020
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spelling oai:doaj.org-article:9e8e0063ee21498a9220e5700df2756d2021-12-02T18:02:12ZEffect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film2302-46902302-4690https://doaj.org/article/9e8e0063ee21498a9220e5700df2756d2020-04-01T00:00:00Zhttps://jpacr.ub.ac.id/index.php/jpacr/article/view/514/pdfhttps://doaj.org/toc/2302-4690https://doaj.org/toc/2302-4690This study carried out on the effect of precursor concentration and annealed substrate temperature on the crystal structure, electronic and optical properties of ZnO thin film. An aqueous solution of Acid Nitrite was used as precursors and its concentration was varied from 0.1 M to 0.4 M. The ZnO thin film was deposited on the glass substrate by Spray Pyrolysis Deposition and annealed with different temperature from 300 oC to 600 oC. The crystal structure, electronic and optical properties were investigated by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and UV-Spectrometer. XRD result showed that all thin films have amorphous hexagonal wurtzite crystalline. Particle sizes ranging from 21.83 to 43.67 nm were calculated through Debye-Scherer Method. It showed that the concentration of the precursor had slightly impact on the particle size. Meanwhile, the increase in particle size with increasing annealed temperature is found to be gradual. The average transparent of all thin film was more than 80%. The bandgap of the ZnO thin films was estimated by Tauc Plot Relation. It showed that the bandgap values were increased with the increasing of precursor concentration due to Burstein-Moss Effect. In addition, the decrease in band gap values was found with increasing annealed temperature. Our results demonstrated that the varying precursor concentration and annealed substrate temperature can enhance the structure, electronic and the optical properties of ZnO thin films.Yus Rama Denny Muchtar Teguh FirmansyahAdhitya TrenggonoDanu WijayaGanesha AntarnusaAndri SuhermanUniversity of Brawijayaarticlezno thin filmsconcentration precursorsannealed temperaturespray pyrolysisChemistryQD1-999ENJournal of Pure and Applied Chemistry Research, Vol 9, Iss 1, Pp 57-65 (2020)
institution DOAJ
collection DOAJ
language EN
topic zno thin films
concentration precursors
annealed temperature
spray pyrolysis
Chemistry
QD1-999
spellingShingle zno thin films
concentration precursors
annealed temperature
spray pyrolysis
Chemistry
QD1-999
Yus Rama Denny Muchtar
Teguh Firmansyah
Adhitya Trenggono
Danu Wijaya
Ganesha Antarnusa
Andri Suherman
Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
description This study carried out on the effect of precursor concentration and annealed substrate temperature on the crystal structure, electronic and optical properties of ZnO thin film. An aqueous solution of Acid Nitrite was used as precursors and its concentration was varied from 0.1 M to 0.4 M. The ZnO thin film was deposited on the glass substrate by Spray Pyrolysis Deposition and annealed with different temperature from 300 oC to 600 oC. The crystal structure, electronic and optical properties were investigated by Scanning Electron Microscopy (SEM), X-ray diffraction (XRD) and UV-Spectrometer. XRD result showed that all thin films have amorphous hexagonal wurtzite crystalline. Particle sizes ranging from 21.83 to 43.67 nm were calculated through Debye-Scherer Method. It showed that the concentration of the precursor had slightly impact on the particle size. Meanwhile, the increase in particle size with increasing annealed temperature is found to be gradual. The average transparent of all thin film was more than 80%. The bandgap of the ZnO thin films was estimated by Tauc Plot Relation. It showed that the bandgap values were increased with the increasing of precursor concentration due to Burstein-Moss Effect. In addition, the decrease in band gap values was found with increasing annealed temperature. Our results demonstrated that the varying precursor concentration and annealed substrate temperature can enhance the structure, electronic and the optical properties of ZnO thin films.
format article
author Yus Rama Denny Muchtar
Teguh Firmansyah
Adhitya Trenggono
Danu Wijaya
Ganesha Antarnusa
Andri Suherman
author_facet Yus Rama Denny Muchtar
Teguh Firmansyah
Adhitya Trenggono
Danu Wijaya
Ganesha Antarnusa
Andri Suherman
author_sort Yus Rama Denny Muchtar
title Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
title_short Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
title_full Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
title_fullStr Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
title_full_unstemmed Effect of Precursor Concentration and Annealed Substrate Temperature on the Crystal Structure, Electronic and Optical Properties of ZnO thin film
title_sort effect of precursor concentration and annealed substrate temperature on the crystal structure, electronic and optical properties of zno thin film
publisher University of Brawijaya
publishDate 2020
url https://doaj.org/article/9e8e0063ee21498a9220e5700df2756d
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