Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering...
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2021
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oai:doaj.org-article:9e9b696d4ebc42d69335be67f0ee22502021-11-25T17:55:32ZMetal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review10.3390/ijms2222123371422-00671661-6596https://doaj.org/article/9e9b696d4ebc42d69335be67f0ee22502021-11-01T00:00:00Zhttps://www.mdpi.com/1422-0067/22/22/12337https://doaj.org/toc/1661-6596https://doaj.org/toc/1422-0067Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view, new alternative catalysts are highly sought after. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. The catalytic activity of carbides results from the synthesis-dependent structural properties of carbides. In this respect, this review presents the most important methods of titanium, molybdenum, and tungsten carbide synthesis and the influence of their properties on activity in catalyzing the reaction of methane with carbon dioxide.Natalia CzaplickaAndrzej RogalaIzabela WysockaMDPI AGarticledry reformingcatalystsmetal carbidesmolybdenumtungstentitaniumBiology (General)QH301-705.5ChemistryQD1-999ENInternational Journal of Molecular Sciences, Vol 22, Iss 12337, p 12337 (2021) |
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dry reforming catalysts metal carbides molybdenum tungsten titanium Biology (General) QH301-705.5 Chemistry QD1-999 |
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dry reforming catalysts metal carbides molybdenum tungsten titanium Biology (General) QH301-705.5 Chemistry QD1-999 Natalia Czaplicka Andrzej Rogala Izabela Wysocka Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
description |
Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view, new alternative catalysts are highly sought after. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. The catalytic activity of carbides results from the synthesis-dependent structural properties of carbides. In this respect, this review presents the most important methods of titanium, molybdenum, and tungsten carbide synthesis and the influence of their properties on activity in catalyzing the reaction of methane with carbon dioxide. |
format |
article |
author |
Natalia Czaplicka Andrzej Rogala Izabela Wysocka |
author_facet |
Natalia Czaplicka Andrzej Rogala Izabela Wysocka |
author_sort |
Natalia Czaplicka |
title |
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
title_short |
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
title_full |
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
title_fullStr |
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
title_full_unstemmed |
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review |
title_sort |
metal (mo, w, ti) carbide catalysts: synthesis and application as alternative catalysts for dry reforming of hydrocarbons—a review |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/9e9b696d4ebc42d69335be67f0ee2250 |
work_keys_str_mv |
AT nataliaczaplicka metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview AT andrzejrogala metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview AT izabelawysocka metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview |
_version_ |
1718411819842797568 |