Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review

Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering...

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Autores principales: Natalia Czaplicka, Andrzej Rogala, Izabela Wysocka
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:9e9b696d4ebc42d69335be67f0ee22502021-11-25T17:55:32ZMetal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review10.3390/ijms2222123371422-00671661-6596https://doaj.org/article/9e9b696d4ebc42d69335be67f0ee22502021-11-01T00:00:00Zhttps://www.mdpi.com/1422-0067/22/22/12337https://doaj.org/toc/1661-6596https://doaj.org/toc/1422-0067Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view, new alternative catalysts are highly sought after. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. The catalytic activity of carbides results from the synthesis-dependent structural properties of carbides. In this respect, this review presents the most important methods of titanium, molybdenum, and tungsten carbide synthesis and the influence of their properties on activity in catalyzing the reaction of methane with carbon dioxide.Natalia CzaplickaAndrzej RogalaIzabela WysockaMDPI AGarticledry reformingcatalystsmetal carbidesmolybdenumtungstentitaniumBiology (General)QH301-705.5ChemistryQD1-999ENInternational Journal of Molecular Sciences, Vol 22, Iss 12337, p 12337 (2021)
institution DOAJ
collection DOAJ
language EN
topic dry reforming
catalysts
metal carbides
molybdenum
tungsten
titanium
Biology (General)
QH301-705.5
Chemistry
QD1-999
spellingShingle dry reforming
catalysts
metal carbides
molybdenum
tungsten
titanium
Biology (General)
QH301-705.5
Chemistry
QD1-999
Natalia Czaplicka
Andrzej Rogala
Izabela Wysocka
Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
description Dry reforming of hydrocarbons (DRH) is a pro-environmental method for syngas production. It owes its pro-environmental character to the use of carbon dioxide, which is one of the main greenhouse gases. Currently used nickel catalysts on oxide supports suffer from rapid deactivation due to sintering of active metal particles or the deposition of carbon deposits blocking the flow of gases through the reaction tube. In this view, new alternative catalysts are highly sought after. Transition metal carbides (TMCs) can potentially replace traditional nickel catalysts due to their stability and activity in DR processes. The catalytic activity of carbides results from the synthesis-dependent structural properties of carbides. In this respect, this review presents the most important methods of titanium, molybdenum, and tungsten carbide synthesis and the influence of their properties on activity in catalyzing the reaction of methane with carbon dioxide.
format article
author Natalia Czaplicka
Andrzej Rogala
Izabela Wysocka
author_facet Natalia Czaplicka
Andrzej Rogala
Izabela Wysocka
author_sort Natalia Czaplicka
title Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
title_short Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
title_full Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
title_fullStr Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
title_full_unstemmed Metal (Mo, W, Ti) Carbide Catalysts: Synthesis and Application as Alternative Catalysts for Dry Reforming of Hydrocarbons—A Review
title_sort metal (mo, w, ti) carbide catalysts: synthesis and application as alternative catalysts for dry reforming of hydrocarbons—a review
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/9e9b696d4ebc42d69335be67f0ee2250
work_keys_str_mv AT nataliaczaplicka metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview
AT andrzejrogala metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview
AT izabelawysocka metalmowticarbidecatalystssynthesisandapplicationasalternativecatalystsfordryreformingofhydrocarbonsareview
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