Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite

In this study, the in situ chemical polymerization process was used to synthesize polystyrene/magnetite nanocomposite (PS-DVB/ Fe3O4). The prepared composite was characterized by XPS, SEM, XRD, HRTEM, FT-IR, and TGA technique. The XPS as an essential elemental analysis tool proved the proposed gener...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Mohamed A. Ali, Mahmoud F. Mubarak, Mohamed Keshawy, Mohamed A. Zayed, Mohamed Ataalla
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2022
Materias:	Nanocomposites Tartrazine Magnetic core–shell Chemisorption theoretical models Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/9ea561e287814a23871deeede37c8fe6
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:9ea561e287814a23871deeede37c8fe6
record_format	dspace
spelling	oai:doaj.org-article:9ea561e287814a23871deeede37c8fe62021-11-20T04:56:09ZAdsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite1110-016810.1016/j.aej.2021.06.016https://doaj.org/article/9ea561e287814a23871deeede37c8fe62022-02-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1110016821003847https://doaj.org/toc/1110-0168In this study, the in situ chemical polymerization process was used to synthesize polystyrene/magnetite nanocomposite (PS-DVB/ Fe3O4). The prepared composite was characterized by XPS, SEM, XRD, HRTEM, FT-IR, and TGA technique. The XPS as an essential elemental analysis tool proved the proposed general formulae of the prepared nanocomposite (PS-DVB/ Fe3O4). FT-IR data proved the functional groups in the proposed structural formula of the prepared nanomaterials. The thermal analysis confirmed the high thermal stability of the prepared core–shell polymer. XRD results prove the crystallinity and single phase. Scanning electron microscope (SEM) and the presence of Fe2O3 and PS-DVB/Fe3O4 composite has been confirmed by HRTEM. The particle size analysis was used to determine the distribution of particle size within the polymer matrix. The adsorption potential of Tartrazine azo dye from polluted water samples onto cross-linked (PS-DVB/Fe3O4) using fixed-bed adsorption column was investigated. The adsorption capacity of Tartrazine onto PS-DVB greatly improved when Fe3O4 is added to the porous composite of PS-DVB copolymer to be 0.15 mol with removal efficiency reach 98%. In this respect, the effect of liquid flow rate, initial Tartrazine concentration, and PS-DVB/Fe3O4 bed height on the adsorption technique's breakthrough features was taken. In this work, the mass transfer model, which involved the two parameters of τ (50% breakthrough time) and k (adsorption rate constant), was suggested for discussion the effect of PS-DVB/Fe3O4on such values. It was found that the adsorption capacity Qe and τ values were decreased with the flow rate increases. The flow rate had little effect, at least for the PS-DVB/Fe3O4, on the k value. On the other hand, both Qe and τ values decreased with increasing the initial Tartrazine concentration, whereas the k value was slightly increased. We concluded that the liquid flow rate, initial Tartrazine concentration, and bed height were1mL/min, 5 M, and 7 cm, respectively. Finally, the PS-DVB/Fe3O4 was a suitable Tartrazine adsorbent using a fixed-bed adsorption column, which fitted well with the mass transfer model.Mohamed A. AliMahmoud F. MubarakMohamed KeshawyMohamed A. ZayedMohamed AtaallaElsevierarticleNanocompositesTartrazineMagnetic core–shellChemisorption theoretical modelsEngineering (General). Civil engineering (General)TA1-2040ENAlexandria Engineering Journal, Vol 61, Iss 2, Pp 1335-1352 (2022)
institution	DOAJ
collection	DOAJ
language	EN
topic	Nanocomposites Tartrazine Magnetic core–shell Chemisorption theoretical models Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	Nanocomposites Tartrazine Magnetic core–shell Chemisorption theoretical models Engineering (General). Civil engineering (General) TA1-2040 Mohamed A. Ali Mahmoud F. Mubarak Mohamed Keshawy Mohamed A. Zayed Mohamed Ataalla Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
description	In this study, the in situ chemical polymerization process was used to synthesize polystyrene/magnetite nanocomposite (PS-DVB/ Fe3O4). The prepared composite was characterized by XPS, SEM, XRD, HRTEM, FT-IR, and TGA technique. The XPS as an essential elemental analysis tool proved the proposed general formulae of the prepared nanocomposite (PS-DVB/ Fe3O4). FT-IR data proved the functional groups in the proposed structural formula of the prepared nanomaterials. The thermal analysis confirmed the high thermal stability of the prepared core–shell polymer. XRD results prove the crystallinity and single phase. Scanning electron microscope (SEM) and the presence of Fe2O3 and PS-DVB/Fe3O4 composite has been confirmed by HRTEM. The particle size analysis was used to determine the distribution of particle size within the polymer matrix. The adsorption potential of Tartrazine azo dye from polluted water samples onto cross-linked (PS-DVB/Fe3O4) using fixed-bed adsorption column was investigated. The adsorption capacity of Tartrazine onto PS-DVB greatly improved when Fe3O4 is added to the porous composite of PS-DVB copolymer to be 0.15 mol with removal efficiency reach 98%. In this respect, the effect of liquid flow rate, initial Tartrazine concentration, and PS-DVB/Fe3O4 bed height on the adsorption technique's breakthrough features was taken. In this work, the mass transfer model, which involved the two parameters of τ (50% breakthrough time) and k (adsorption rate constant), was suggested for discussion the effect of PS-DVB/Fe3O4on such values. It was found that the adsorption capacity Qe and τ values were decreased with the flow rate increases. The flow rate had little effect, at least for the PS-DVB/Fe3O4, on the k value. On the other hand, both Qe and τ values decreased with increasing the initial Tartrazine concentration, whereas the k value was slightly increased. We concluded that the liquid flow rate, initial Tartrazine concentration, and bed height were1mL/min, 5 M, and 7 cm, respectively. Finally, the PS-DVB/Fe3O4 was a suitable Tartrazine adsorbent using a fixed-bed adsorption column, which fitted well with the mass transfer model.
format	article
author	Mohamed A. Ali Mahmoud F. Mubarak Mohamed Keshawy Mohamed A. Zayed Mohamed Ataalla
author_facet	Mohamed A. Ali Mahmoud F. Mubarak Mohamed Keshawy Mohamed A. Zayed Mohamed Ataalla
author_sort	Mohamed A. Ali
title	Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
title_short	Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
title_full	Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
title_fullStr	Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
title_full_unstemmed	Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite
title_sort	adsorption of tartrazine anionic dye by novel fixed bed core-shell- polystyrene divinylbenzene/magnetite nanocomposite
publisher	Elsevier
publishDate	2022
url	https://doaj.org/article/9ea561e287814a23871deeede37c8fe6
work_keys_str_mv	AT mohamedaali adsorptionoftartrazineanionicdyebynovelfixedbedcoreshellpolystyrenedivinylbenzenemagnetitenanocomposite AT mahmoudfmubarak adsorptionoftartrazineanionicdyebynovelfixedbedcoreshellpolystyrenedivinylbenzenemagnetitenanocomposite AT mohamedkeshawy adsorptionoftartrazineanionicdyebynovelfixedbedcoreshellpolystyrenedivinylbenzenemagnetitenanocomposite AT mohamedazayed adsorptionoftartrazineanionicdyebynovelfixedbedcoreshellpolystyrenedivinylbenzenemagnetitenanocomposite AT mohamedataalla adsorptionoftartrazineanionicdyebynovelfixedbedcoreshellpolystyrenedivinylbenzenemagnetitenanocomposite
_version_	1718419731244908544

Adsorption of Tartrazine anionic dye by novel fixed bed Core-Shell- polystyrene Divinylbenzene/Magnetite nanocomposite

Ejemplares similares