TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides

An efficient TBAI-catalyzed ring-opening sulfonylation of benzo[d]thiazole and arylsulfonyl hydrazide has been developed. Various benzo[d]thiazole as good thiol surrogates are compatible with the catalytic conditions, providing diversified unsymmetrical thiosulfonates with good yields. This strategy...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Xuezhen Li, Ping Liu, Jing He, Weiwei Li, Zhen Yang, Yueting Wei, Yu Wei, Yanlong Gu
Formato:	article
Lenguaje:	EN
Publicado:	KeAi Communications Co. Ltd. 2021
Materias:	Benzothiazoles Ring-opening Sulfonylation Arylsulfonyl hydrazide Thiosulfonate Chemical technology TP1-1185 Biochemistry QD415-436
Acceso en línea:	https://doaj.org/article/9ed39f5707144827842b13718c080feb
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:9ed39f5707144827842b13718c080feb
record_format	dspace
spelling	oai:doaj.org-article:9ed39f5707144827842b13718c080feb2021-12-02T05:03:57ZTBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides2666-554910.1016/j.gresc.2021.08.006https://doaj.org/article/9ed39f5707144827842b13718c080feb2021-11-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666554921000788https://doaj.org/toc/2666-5549An efficient TBAI-catalyzed ring-opening sulfonylation of benzo[d]thiazole and arylsulfonyl hydrazide has been developed. Various benzo[d]thiazole as good thiol surrogates are compatible with the catalytic conditions, providing diversified unsymmetrical thiosulfonates with good yields. This strategy features mild reaction conditions, broad substrate scope, readily available starting materials, and gram-scale synthesis. Importantly, these products can be readily converted to novel o-amino-substituted diaryl sulfides.Xuezhen LiPing LiuJing HeWeiwei LiZhen YangYueting WeiYu WeiYanlong GuKeAi Communications Co. Ltd.articleBenzothiazolesRing-openingSulfonylationArylsulfonyl hydrazideThiosulfonateChemical technologyTP1-1185BiochemistryQD415-436ENGreen Synthesis and Catalysis, Vol 2, Iss 4, Pp 381-384 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Benzothiazoles Ring-opening Sulfonylation Arylsulfonyl hydrazide Thiosulfonate Chemical technology TP1-1185 Biochemistry QD415-436
spellingShingle	Benzothiazoles Ring-opening Sulfonylation Arylsulfonyl hydrazide Thiosulfonate Chemical technology TP1-1185 Biochemistry QD415-436 Xuezhen Li Ping Liu Jing He Weiwei Li Zhen Yang Yueting Wei Yu Wei Yanlong Gu TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
description	An efficient TBAI-catalyzed ring-opening sulfonylation of benzo[d]thiazole and arylsulfonyl hydrazide has been developed. Various benzo[d]thiazole as good thiol surrogates are compatible with the catalytic conditions, providing diversified unsymmetrical thiosulfonates with good yields. This strategy features mild reaction conditions, broad substrate scope, readily available starting materials, and gram-scale synthesis. Importantly, these products can be readily converted to novel o-amino-substituted diaryl sulfides.
format	article
author	Xuezhen Li Ping Liu Jing He Weiwei Li Zhen Yang Yueting Wei Yu Wei Yanlong Gu
author_facet	Xuezhen Li Ping Liu Jing He Weiwei Li Zhen Yang Yueting Wei Yu Wei Yanlong Gu
author_sort	Xuezhen Li
title	TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
title_short	TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
title_full	TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
title_fullStr	TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
title_full_unstemmed	TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
title_sort	tbai-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides
publisher	KeAi Communications Co. Ltd.
publishDate	2021
url	https://doaj.org/article/9ed39f5707144827842b13718c080feb
work_keys_str_mv	AT xuezhenli tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT pingliu tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT jinghe tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT weiweili tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT zhenyang tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT yuetingwei tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT yuwei tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides AT yanlonggu tbaicatalyzedringopeningsulfonylationsofbenzothiazolesandarylsulfonylhydrazides
_version_	1718400665851527168

TBAI-catalyzed ring-opening sulfonylations of benzothiazoles and arylsulfonyl hydrazides

Ejemplares similares