The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks

Metal-Organic Frameworks (MOFs) as a class of crystalline materials are constructed using metal nodes and organic spacers. Polydentate N-donor ligands play a mainstay-type role in the construction of metal−organic frameworks, especially cationic MOFs. Highly stable cationic MOFs with high porosity a...

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Autores principales:	Hongru Fu, Yuying Jiang, Fei Wang, Jian Zhang
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	Metal-Organic Frameworks tris (4-(1H-imidazol-1-yl) phenyl) amine porous crystalline materials Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/9ef3daa3499e45178d5e71e0c09b8b3c
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spelling	oai:doaj.org-article:9ef3daa3499e45178d5e71e0c09b8b3c2021-11-25T18:29:49ZThe Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks10.3390/nano111127912079-4991https://doaj.org/article/9ef3daa3499e45178d5e71e0c09b8b3c2021-10-01T00:00:00Zhttps://www.mdpi.com/2079-4991/11/11/2791https://doaj.org/toc/2079-4991Metal-Organic Frameworks (MOFs) as a class of crystalline materials are constructed using metal nodes and organic spacers. Polydentate N-donor ligands play a mainstay-type role in the construction of metal−organic frameworks, especially cationic MOFs. Highly stable cationic MOFs with high porosity and open channels exhibit distinct advantages, they can act as a powerful ion exchange platform for the capture of toxic heavy-metal oxoanions through a Single-Crystal to Single-Crystal (SC-SC) pattern. Porous luminescent MOFs can act as nano-sized containers to encapsulate guest emitters and construct multi-emitter materials for chemical sensing. This feature article reviews the synthesis and application of porous Metal-Organic Frameworks based on tridentate ligand tris (4-(1H-imidazol-1-yl) phenyl) amine (TIPA) and focuses on design strategies for the synthesis of TIPA-dominated Metal-Organic Frameworks with high porosity and stability. The design strategies are integrated into four types: small organic molecule as auxiliaries, inorganic oxyanion as auxiliaries, small organic molecule as secondary linkers, and metal clusters as nodes. The applications of ratiometric sensing, the adsorption of oxyanions contaminants from water, and small molecule gas storage are summarized. We hope to provide experience and inspiration in the design and construction of highly porous MOFs base on polydentate N-donor ligands.Hongru FuYuying JiangFei WangJian ZhangMDPI AGarticleMetal-Organic Frameworkstris (4-(1H-imidazol-1-yl) phenyl) amineporous crystalline materialsChemistryQD1-999ENNanomaterials, Vol 11, Iss 2791, p 2791 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Metal-Organic Frameworks tris (4-(1H-imidazol-1-yl) phenyl) amine porous crystalline materials Chemistry QD1-999
spellingShingle	Metal-Organic Frameworks tris (4-(1H-imidazol-1-yl) phenyl) amine porous crystalline materials Chemistry QD1-999 Hongru Fu Yuying Jiang Fei Wang Jian Zhang The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
description	Metal-Organic Frameworks (MOFs) as a class of crystalline materials are constructed using metal nodes and organic spacers. Polydentate N-donor ligands play a mainstay-type role in the construction of metal−organic frameworks, especially cationic MOFs. Highly stable cationic MOFs with high porosity and open channels exhibit distinct advantages, they can act as a powerful ion exchange platform for the capture of toxic heavy-metal oxoanions through a Single-Crystal to Single-Crystal (SC-SC) pattern. Porous luminescent MOFs can act as nano-sized containers to encapsulate guest emitters and construct multi-emitter materials for chemical sensing. This feature article reviews the synthesis and application of porous Metal-Organic Frameworks based on tridentate ligand tris (4-(1H-imidazol-1-yl) phenyl) amine (TIPA) and focuses on design strategies for the synthesis of TIPA-dominated Metal-Organic Frameworks with high porosity and stability. The design strategies are integrated into four types: small organic molecule as auxiliaries, inorganic oxyanion as auxiliaries, small organic molecule as secondary linkers, and metal clusters as nodes. The applications of ratiometric sensing, the adsorption of oxyanions contaminants from water, and small molecule gas storage are summarized. We hope to provide experience and inspiration in the design and construction of highly porous MOFs base on polydentate N-donor ligands.
format	article
author	Hongru Fu Yuying Jiang Fei Wang Jian Zhang
author_facet	Hongru Fu Yuying Jiang Fei Wang Jian Zhang
author_sort	Hongru Fu
title	The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
title_short	The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
title_full	The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
title_fullStr	The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
title_full_unstemmed	The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks
title_sort	synthesis and properties of tipa-dominated porous metal-organic frameworks
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9ef3daa3499e45178d5e71e0c09b8b3c
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The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks

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