Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition

Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddi...

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Autores principales:	Alessia Tombesi, Claudio Pettinari
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	heterogenous catalyst metal–organic framework (MOF) olefin epoxidation carbon dioxide cycloaddition Inorganic chemistry QD146-197
Acceso en línea:	https://doaj.org/article/9f7ed63f54884253907f1e9a215a9fca
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spelling	oai:doaj.org-article:9f7ed63f54884253907f1e9a215a9fca2021-11-25T17:58:58ZMetal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition10.3390/inorganics91100812304-6740https://doaj.org/article/9f7ed63f54884253907f1e9a215a9fca2021-11-01T00:00:00Zhttps://www.mdpi.com/2304-6740/9/11/81https://doaj.org/toc/2304-6740Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO<sub>2</sub> consuming reactions.Alessia TombesiClaudio PettinariMDPI AGarticleheterogenous catalystmetal–organic framework (MOF)olefin epoxidationcarbon dioxide cycloadditionInorganic chemistryQD146-197ENInorganics, Vol 9, Iss 81, p 81 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	heterogenous catalyst metal–organic framework (MOF) olefin epoxidation carbon dioxide cycloaddition Inorganic chemistry QD146-197
spellingShingle	heterogenous catalyst metal–organic framework (MOF) olefin epoxidation carbon dioxide cycloaddition Inorganic chemistry QD146-197 Alessia Tombesi Claudio Pettinari Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
description	Metal–organic frameworks (MOFs) are a family of porous crystalline materials that serve in some cases as versatile platforms for catalysis. In this review, we overview the recent developments about the use of these species as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition. We report the most important results obtained in this field relating them to the presence of specific organic linkers, metal nodes or clusters and mixed-metal species. Recent advances obtained with MOF nanocomposites were also described. Finally we compare the results and summarize the major insights in specific Tables, outlining the major challenges for this emerging field. This work could promote new research aimed at producing coordination polymers and MOFs able to catalyse a broader range of CO<sub>2</sub> consuming reactions.
format	article
author	Alessia Tombesi Claudio Pettinari
author_facet	Alessia Tombesi Claudio Pettinari
author_sort	Alessia Tombesi
title	Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
title_short	Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
title_full	Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
title_fullStr	Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
title_full_unstemmed	Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition
title_sort	metal organic frameworks as heterogeneous catalysts in olefin epoxidation and carbon dioxide cycloaddition
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/9f7ed63f54884253907f1e9a215a9fca
work_keys_str_mv	AT alessiatombesi metalorganicframeworksasheterogeneouscatalystsinolefinepoxidationandcarbondioxidecycloaddition AT claudiopettinari metalorganicframeworksasheterogeneouscatalystsinolefinepoxidationandcarbondioxidecycloaddition
_version_	1718411763265830912

Metal Organic Frameworks as Heterogeneous Catalysts in Olefin Epoxidation and Carbon Dioxide Cycloaddition

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