The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites

The influence of poly(ε-caprolactone) (PCL) grafts on the rheology and crystallization behavior of nanocomposites based on PCL and cellulose nanocrystals (CNC) both under quiescent and shear conditions is investigated. Under quiescent conditions, the grafted nanocrystals have high nucleation efficie...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Maria Eriksson, Anne-Lise Goffin, Philippe Dubois, Ton Peijs, Han Goossens
Formato:	article
Lenguaje:	EN
Publicado:	Taylor & Francis Group 2018
Materias:	Poly(ε-caprolactone) cellulose nanocrystals grafting flow-induced crystallization SAXS Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185
Acceso en línea:	https://doaj.org/article/9f89a457b73e43869318aa37cd270a92
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:9f89a457b73e43869318aa37cd270a92
record_format	dspace
spelling	oai:doaj.org-article:9f89a457b73e43869318aa37cd270a922021-12-02T06:18:18ZThe influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites2055-03242055-033210.1080/20550324.2018.1529713https://doaj.org/article/9f89a457b73e43869318aa37cd270a922018-07-01T00:00:00Zhttp://dx.doi.org/10.1080/20550324.2018.1529713https://doaj.org/toc/2055-0324https://doaj.org/toc/2055-0332The influence of poly(ε-caprolactone) (PCL) grafts on the rheology and crystallization behavior of nanocomposites based on PCL and cellulose nanocrystals (CNC) both under quiescent and shear conditions is investigated. Under quiescent conditions, the grafted nanocrystals have high nucleation efficiencies. Under the influence of shear, the non-grafted nanocrystals were, however, more efficient in orienting the polymer chains and accelerating the flow-induced crystallization. The addition of large amounts of grafted material decreases the viscosity of the composites and thereby also the efficiency of shear-induced orientation.Maria ErikssonAnne-Lise GoffinPhilippe DuboisTon PeijsHan GoossensTaylor & Francis GrouparticlePoly(ε-caprolactone)cellulose nanocrystalsgraftingflow-induced crystallizationSAXSMaterials of engineering and construction. Mechanics of materialsTA401-492Polymers and polymer manufactureTP1080-1185ENNanocomposites, Vol 4, Iss 3, Pp 87-101 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Poly(ε-caprolactone) cellulose nanocrystals grafting flow-induced crystallization SAXS Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185
spellingShingle	Poly(ε-caprolactone) cellulose nanocrystals grafting flow-induced crystallization SAXS Materials of engineering and construction. Mechanics of materials TA401-492 Polymers and polymer manufacture TP1080-1185 Maria Eriksson Anne-Lise Goffin Philippe Dubois Ton Peijs Han Goossens The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
description	The influence of poly(ε-caprolactone) (PCL) grafts on the rheology and crystallization behavior of nanocomposites based on PCL and cellulose nanocrystals (CNC) both under quiescent and shear conditions is investigated. Under quiescent conditions, the grafted nanocrystals have high nucleation efficiencies. Under the influence of shear, the non-grafted nanocrystals were, however, more efficient in orienting the polymer chains and accelerating the flow-induced crystallization. The addition of large amounts of grafted material decreases the viscosity of the composites and thereby also the efficiency of shear-induced orientation.
format	article
author	Maria Eriksson Anne-Lise Goffin Philippe Dubois Ton Peijs Han Goossens
author_facet	Maria Eriksson Anne-Lise Goffin Philippe Dubois Ton Peijs Han Goossens
author_sort	Maria Eriksson
title	The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
title_short	The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
title_full	The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
title_fullStr	The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
title_full_unstemmed	The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
title_sort	influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
publisher	Taylor & Francis Group
publishDate	2018
url	https://doaj.org/article/9f89a457b73e43869318aa37cd270a92
work_keys_str_mv	AT mariaeriksson theinfluenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT annelisegoffin theinfluenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT philippedubois theinfluenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT tonpeijs theinfluenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT hangoossens theinfluenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT mariaeriksson influenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT annelisegoffin influenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT philippedubois influenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT tonpeijs influenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites AT hangoossens influenceofgraftingonflowinducedcrystallizationandrheologicalpropertiesofpolyecaprolactonecellulosenanocrystalnanocomposites
_version_	1718400005245501440

The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites

Ejemplares similares