Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates

Gold nanoclusters are known to grow stepwise from gold-thiolate monomers and oligomers. Here, the authors find that the evolution of silver nanoclusters differs completely from that of gold: rather than following a bottom-up pathway, the clusters evolve from similarly-sized Ag-thiolate cluster inter...

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Autores principales: Yitao Cao, Jiahao Guo, Run Shi, Geoffrey I. N. Waterhouse, Jinheng Pan, Zhenxia Du, Qiaofeng Yao, Li-Zhu Wu, Chen-Ho Tung, Jianping Xie, Tierui Zhang
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Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/9fea06c9c26f47ef890eac2dde8f7c52
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spelling oai:doaj.org-article:9fea06c9c26f47ef890eac2dde8f7c522021-12-02T15:34:07ZEvolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates10.1038/s41467-018-04837-x2041-1723https://doaj.org/article/9fea06c9c26f47ef890eac2dde8f7c522018-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04837-xhttps://doaj.org/toc/2041-1723Gold nanoclusters are known to grow stepwise from gold-thiolate monomers and oligomers. Here, the authors find that the evolution of silver nanoclusters differs completely from that of gold: rather than following a bottom-up pathway, the clusters evolve from similarly-sized Ag-thiolate cluster intermediates.Yitao CaoJiahao GuoRun ShiGeoffrey I. N. WaterhouseJinheng PanZhenxia DuQiaofeng YaoLi-Zhu WuChen-Ho TungJianping XieTierui ZhangNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yitao Cao
Jiahao Guo
Run Shi
Geoffrey I. N. Waterhouse
Jinheng Pan
Zhenxia Du
Qiaofeng Yao
Li-Zhu Wu
Chen-Ho Tung
Jianping Xie
Tierui Zhang
Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
description Gold nanoclusters are known to grow stepwise from gold-thiolate monomers and oligomers. Here, the authors find that the evolution of silver nanoclusters differs completely from that of gold: rather than following a bottom-up pathway, the clusters evolve from similarly-sized Ag-thiolate cluster intermediates.
format article
author Yitao Cao
Jiahao Guo
Run Shi
Geoffrey I. N. Waterhouse
Jinheng Pan
Zhenxia Du
Qiaofeng Yao
Li-Zhu Wu
Chen-Ho Tung
Jianping Xie
Tierui Zhang
author_facet Yitao Cao
Jiahao Guo
Run Shi
Geoffrey I. N. Waterhouse
Jinheng Pan
Zhenxia Du
Qiaofeng Yao
Li-Zhu Wu
Chen-Ho Tung
Jianping Xie
Tierui Zhang
author_sort Yitao Cao
title Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
title_short Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
title_full Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
title_fullStr Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
title_full_unstemmed Evolution of thiolate-stabilized Ag nanoclusters from Ag-thiolate cluster intermediates
title_sort evolution of thiolate-stabilized ag nanoclusters from ag-thiolate cluster intermediates
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/9fea06c9c26f47ef890eac2dde8f7c52
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