Defluorosilylation of fluoroarenes and fluoroalkanes

Transformation of strong C-F bonds into C-Si bonds is an extremely useful strategy for further derivatization of organic molecules. Here, the authors report a nickel-catalyzed strategy to convert aryl fluorides into sylylated arenes while defluorosilylation of alkyl fluorides is achieved under metal...

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Autores principales:	Benqiang Cui, Shichong Jia, Etsuko Tokunaga, Norio Shibata
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a0a3d223358c4f41bfbcfd034403093b
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spelling	oai:doaj.org-article:a0a3d223358c4f41bfbcfd034403093b2021-12-02T14:40:02ZDefluorosilylation of fluoroarenes and fluoroalkanes10.1038/s41467-018-06830-w2041-1723https://doaj.org/article/a0a3d223358c4f41bfbcfd034403093b2018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06830-whttps://doaj.org/toc/2041-1723Transformation of strong C-F bonds into C-Si bonds is an extremely useful strategy for further derivatization of organic molecules. Here, the authors report a nickel-catalyzed strategy to convert aryl fluorides into sylylated arenes while defluorosilylation of alkyl fluorides is achieved under metal-free conditions.Benqiang CuiShichong JiaEtsuko TokunagaNorio ShibataNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Benqiang Cui Shichong Jia Etsuko Tokunaga Norio Shibata Defluorosilylation of fluoroarenes and fluoroalkanes
description	Transformation of strong C-F bonds into C-Si bonds is an extremely useful strategy for further derivatization of organic molecules. Here, the authors report a nickel-catalyzed strategy to convert aryl fluorides into sylylated arenes while defluorosilylation of alkyl fluorides is achieved under metal-free conditions.
format	article
author	Benqiang Cui Shichong Jia Etsuko Tokunaga Norio Shibata
author_facet	Benqiang Cui Shichong Jia Etsuko Tokunaga Norio Shibata
author_sort	Benqiang Cui
title	Defluorosilylation of fluoroarenes and fluoroalkanes
title_short	Defluorosilylation of fluoroarenes and fluoroalkanes
title_full	Defluorosilylation of fluoroarenes and fluoroalkanes
title_fullStr	Defluorosilylation of fluoroarenes and fluoroalkanes
title_full_unstemmed	Defluorosilylation of fluoroarenes and fluoroalkanes
title_sort	defluorosilylation of fluoroarenes and fluoroalkanes
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/a0a3d223358c4f41bfbcfd034403093b
work_keys_str_mv	AT benqiangcui defluorosilylationoffluoroarenesandfluoroalkanes AT shichongjia defluorosilylationoffluoroarenesandfluoroalkanes AT etsukotokunaga defluorosilylationoffluoroarenesandfluoroalkanes AT norioshibata defluorosilylationoffluoroarenesandfluoroalkanes
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Defluorosilylation of fluoroarenes and fluoroalkanes

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