Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal

To meet the requirements of automatic production, a new type of green BAl88Si cored solder was developed. The lap brazing experiments were carried out with copper and aluminum as brazing substrates. The microstructure, phase composition, and corrosion behavior of solder joint interface were studied...

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Autores principales: Yu Hua, Zhang Liangliang, Li Shuai, Cai Fangfang, Li Yunpeng, Shi Yinkai, Zhong Sujuan, Ma Jia, Jiu Yongtao, Long Weimin, Dong Honggang, Wei Shizhong
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Lenguaje:EN
Publicado: De Gruyter 2021
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Acceso en línea:https://doaj.org/article/a0abc9f83669428591d502396bfde76e
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spelling oai:doaj.org-article:a0abc9f83669428591d502396bfde76e2021-12-05T14:10:58ZPhase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal2191-909710.1515/ntrev-2021-0081https://doaj.org/article/a0abc9f83669428591d502396bfde76e2021-09-01T00:00:00Zhttps://doi.org/10.1515/ntrev-2021-0081https://doaj.org/toc/2191-9097To meet the requirements of automatic production, a new type of green BAl88Si cored solder was developed. The lap brazing experiments were carried out with copper and aluminum as brazing substrates. The microstructure, phase composition, and corrosion behavior of solder joint interface were studied by field emission scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, electron backscattering diffraction, tensile testing machine, and electrochemical workstation. The results show that the brazing joint of Cu/BAl88Si/Al is metallurgical bonding, and the brazing joint of Cu/BAl88Si/Al is composed of Cu9Al4, CuAl2, a-Al, (CuAl2 + a-Al + Si) ternary eutectic. In addition, there is no obvious preference for each grain in the brazing joint, and there are S texture {123}<634>, Copper texture {112}<111>, and Brass texture {110}<112>. The interface of Cu9Al4/CuAl2 is a non-coherent crystal plane and does not have good lattice matching. The average particle size of CuAl2 is 11.95 µm and that of Al is 28.3 µm. However, the kernel average misorientation (KAM) value at the brazed joint interface is obviously higher than that at the brazed joint interface copper, so the defect density at the brazed joint interface aluminum is higher than that at the brazed joint interface copper. At the same time, due to poor corrosion resistance at the interface on the aluminum side of the brazed joint, serious corrosion spots and corrosion cracks occur at the same time, which leads to the shear performance of the brazed joint decreasing by about 75% after salt spray test for 240 h.Yu HuaZhang LiangliangLi ShuaiCai FangfangLi YunpengShi YinkaiZhong SujuanMa JiaJiu YongtaoLong WeiminDong HonggangWei ShizhongDe Gruyterarticleflux filler metalimclattice mismatchpreferential orientationkamcorrosion behaviorTechnologyTChemical technologyTP1-1185Physical and theoretical chemistryQD450-801ENNanotechnology Reviews, Vol 10, Iss 1, Pp 1318-1328 (2021)
institution DOAJ
collection DOAJ
language EN
topic flux filler metal
imc
lattice mismatch
preferential orientation
kam
corrosion behavior
Technology
T
Chemical technology
TP1-1185
Physical and theoretical chemistry
QD450-801
spellingShingle flux filler metal
imc
lattice mismatch
preferential orientation
kam
corrosion behavior
Technology
T
Chemical technology
TP1-1185
Physical and theoretical chemistry
QD450-801
Yu Hua
Zhang Liangliang
Li Shuai
Cai Fangfang
Li Yunpeng
Shi Yinkai
Zhong Sujuan
Ma Jia
Jiu Yongtao
Long Weimin
Dong Honggang
Wei Shizhong
Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
description To meet the requirements of automatic production, a new type of green BAl88Si cored solder was developed. The lap brazing experiments were carried out with copper and aluminum as brazing substrates. The microstructure, phase composition, and corrosion behavior of solder joint interface were studied by field emission scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, electron backscattering diffraction, tensile testing machine, and electrochemical workstation. The results show that the brazing joint of Cu/BAl88Si/Al is metallurgical bonding, and the brazing joint of Cu/BAl88Si/Al is composed of Cu9Al4, CuAl2, a-Al, (CuAl2 + a-Al + Si) ternary eutectic. In addition, there is no obvious preference for each grain in the brazing joint, and there are S texture {123}<634>, Copper texture {112}<111>, and Brass texture {110}<112>. The interface of Cu9Al4/CuAl2 is a non-coherent crystal plane and does not have good lattice matching. The average particle size of CuAl2 is 11.95 µm and that of Al is 28.3 µm. However, the kernel average misorientation (KAM) value at the brazed joint interface is obviously higher than that at the brazed joint interface copper, so the defect density at the brazed joint interface aluminum is higher than that at the brazed joint interface copper. At the same time, due to poor corrosion resistance at the interface on the aluminum side of the brazed joint, serious corrosion spots and corrosion cracks occur at the same time, which leads to the shear performance of the brazed joint decreasing by about 75% after salt spray test for 240 h.
format article
author Yu Hua
Zhang Liangliang
Li Shuai
Cai Fangfang
Li Yunpeng
Shi Yinkai
Zhong Sujuan
Ma Jia
Jiu Yongtao
Long Weimin
Dong Honggang
Wei Shizhong
author_facet Yu Hua
Zhang Liangliang
Li Shuai
Cai Fangfang
Li Yunpeng
Shi Yinkai
Zhong Sujuan
Ma Jia
Jiu Yongtao
Long Weimin
Dong Honggang
Wei Shizhong
author_sort Yu Hua
title Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
title_short Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
title_full Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
title_fullStr Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
title_full_unstemmed Phase analysis and corrosion behavior of brazing Cu/Al dissimilar metal joint with BAl88Si filler metal
title_sort phase analysis and corrosion behavior of brazing cu/al dissimilar metal joint with bal88si filler metal
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/a0abc9f83669428591d502396bfde76e
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