Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution
Abstract Strong acids are commonly used in petroleum wells to remove scale layers from the surface of N80 C-steel pipe. The corrosive effects of these acids, on the other hand, pose a significant risk to C-steel pipes. For the first time, we discovered the anti-corrosion properties of cationic Gemin...
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2021
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oai:doaj.org-article:a0aec7d555d84ec486a7ab885c87bcff2021-12-02T15:45:27ZInhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution10.1038/s41598-021-90031-x2045-2322https://doaj.org/article/a0aec7d555d84ec486a7ab885c87bcff2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-90031-xhttps://doaj.org/toc/2045-2322Abstract Strong acids are commonly used in petroleum wells to remove scale layers from the surface of N80 C-steel pipe. The corrosive effects of these acids, on the other hand, pose a significant risk to C-steel pipes. For the first time, we discovered the anti-corrosion properties of cationic Gemini surfactant, 1,2-bis(dodecyldimethylammonio) ethane dibromide (DMAEB), for N80 C-steel pipe in acid washing solution (15.0% HCl). The DMAEB, in particular, can reduce the corrosion rate of N80 C-steel by approximately 97%. DMAEB molecules work as a mixed-type corrosion inhibitor, according to electrochemical results. The DMAEB demonstrated a high inhibition effect at high temperatures, as well as high activation energy against the corrosion process. DMAEB's significant performance is primarily due to physical adsorption on the N80 C-steel surface, as confirmed by adsorption isotherms, SEM, EDX, FT-IR, and theoretical studies. Our findings shed new light on the use of Gemini surfactants as corrosion inhibitors in petroleum wells.M. A. DeyabQ. MohsenNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-12 (2021) |
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Medicine R Science Q M. A. Deyab Q. Mohsen Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
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Abstract Strong acids are commonly used in petroleum wells to remove scale layers from the surface of N80 C-steel pipe. The corrosive effects of these acids, on the other hand, pose a significant risk to C-steel pipes. For the first time, we discovered the anti-corrosion properties of cationic Gemini surfactant, 1,2-bis(dodecyldimethylammonio) ethane dibromide (DMAEB), for N80 C-steel pipe in acid washing solution (15.0% HCl). The DMAEB, in particular, can reduce the corrosion rate of N80 C-steel by approximately 97%. DMAEB molecules work as a mixed-type corrosion inhibitor, according to electrochemical results. The DMAEB demonstrated a high inhibition effect at high temperatures, as well as high activation energy against the corrosion process. DMAEB's significant performance is primarily due to physical adsorption on the N80 C-steel surface, as confirmed by adsorption isotherms, SEM, EDX, FT-IR, and theoretical studies. Our findings shed new light on the use of Gemini surfactants as corrosion inhibitors in petroleum wells. |
format |
article |
author |
M. A. Deyab Q. Mohsen |
author_facet |
M. A. Deyab Q. Mohsen |
author_sort |
M. A. Deyab |
title |
Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
title_short |
Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
title_full |
Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
title_fullStr |
Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
title_full_unstemmed |
Inhibitory influence of cationic Gemini surfactant on the dissolution rate of N80 carbon steel in 15% HCl solution |
title_sort |
inhibitory influence of cationic gemini surfactant on the dissolution rate of n80 carbon steel in 15% hcl solution |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/a0aec7d555d84ec486a7ab885c87bcff |
work_keys_str_mv |
AT madeyab inhibitoryinfluenceofcationicgeminisurfactantonthedissolutionrateofn80carbonsteelin15hclsolution AT qmohsen inhibitoryinfluenceofcationicgeminisurfactantonthedissolutionrateofn80carbonsteelin15hclsolution |
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1718385768018214912 |