Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

Palladium catalyzed allylic substitution reactions typically proceed via an outer sphere mechanism, yielding predominately linear products. Here, the authors report an inner sphere process for the allylic substitution of ketone enolates, giving branched products with up to three contiguous stereocen...

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Autores principales:	Da-Chang Bai, Fei-Le Yu, Wan-Ying Wang, Di Chen, Hao Li, Qing-Rong Liu, Chang-Hua Ding, Bo Chen, Xue-Long Hou
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a2190ea2df8449c6b683e64e74797d1d
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spelling	oai:doaj.org-article:a2190ea2df8449c6b683e64e74797d1d2021-12-02T16:57:04ZPalladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism10.1038/ncomms118062041-1723https://doaj.org/article/a2190ea2df8449c6b683e64e74797d1d2016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11806https://doaj.org/toc/2041-1723Palladium catalyzed allylic substitution reactions typically proceed via an outer sphere mechanism, yielding predominately linear products. Here, the authors report an inner sphere process for the allylic substitution of ketone enolates, giving branched products with up to three contiguous stereocentres.Da-Chang BaiFei-Le YuWan-Ying WangDi ChenHao LiQing-Rong LiuChang-Hua DingBo ChenXue-Long HouNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Da-Chang Bai Fei-Le Yu Wan-Ying Wang Di Chen Hao Li Qing-Rong Liu Chang-Hua Ding Bo Chen Xue-Long Hou Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
description	Palladium catalyzed allylic substitution reactions typically proceed via an outer sphere mechanism, yielding predominately linear products. Here, the authors report an inner sphere process for the allylic substitution of ketone enolates, giving branched products with up to three contiguous stereocentres.
format	article
author	Da-Chang Bai Fei-Le Yu Wan-Ying Wang Di Chen Hao Li Qing-Rong Liu Chang-Hua Ding Bo Chen Xue-Long Hou
author_facet	Da-Chang Bai Fei-Le Yu Wan-Ying Wang Di Chen Hao Li Qing-Rong Liu Chang-Hua Ding Bo Chen Xue-Long Hou
author_sort	Da-Chang Bai
title	Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
title_short	Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
title_full	Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
title_fullStr	Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
title_full_unstemmed	Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
title_sort	palladium/n-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/a2190ea2df8449c6b683e64e74797d1d
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Palladium/N-heterocyclic carbene catalysed regio and diastereoselective reaction of ketones with allyl reagents via inner-sphere mechanism

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