A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis

A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis

Supramolecular interactions may be responsible for higher degree of efficiency and selectivity in homogeneous catalysis. Here, the authors exploit the concept of supramolecular catalysis to develop a domino rhodium-catalyzed hydroformylation of α-alkynoic acids followed by Michael addition of nucleo...

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Autores principales: Weiwei Fang, Felix Bauer, Yaxi Dong, Bernhard Breit
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/a3096c1d18d6434a9984845fcc905678
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spelling oai:doaj.org-article:a3096c1d18d6434a9984845fcc9056782021-12-02T17:01:51ZA domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis10.1038/s41467-019-12770-w2041-1723https://doaj.org/article/a3096c1d18d6434a9984845fcc9056782019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12770-whttps://doaj.org/toc/2041-1723Supramolecular interactions may be responsible for higher degree of efficiency and selectivity in homogeneous catalysis. Here, the authors exploit the concept of supramolecular catalysis to develop a domino rhodium-catalyzed hydroformylation of α-alkynoic acids followed by Michael addition of nucleophiles.Weiwei FangFelix BauerYaxi DongBernhard BreitNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Weiwei Fang
Felix Bauer
Yaxi Dong
Bernhard Breit
A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
description Supramolecular interactions may be responsible for higher degree of efficiency and selectivity in homogeneous catalysis. Here, the authors exploit the concept of supramolecular catalysis to develop a domino rhodium-catalyzed hydroformylation of α-alkynoic acids followed by Michael addition of nucleophiles.
format article
author Weiwei Fang
Felix Bauer
Yaxi Dong
Bernhard Breit
author_facet Weiwei Fang
Felix Bauer
Yaxi Dong
Bernhard Breit
author_sort Weiwei Fang
title A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
title_short A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
title_full A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
title_fullStr A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
title_full_unstemmed A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
title_sort domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/a3096c1d18d6434a9984845fcc905678
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AT felixbauer adominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT yaxidong adominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT bernhardbreit adominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT weiweifang dominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT felixbauer dominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT yaxidong dominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
AT bernhardbreit dominoreactionforgeneratingbarylaldehydesfromalkynesbysubstraterecognitioncatalysis
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