Metal/oxide interfacial effects on the selective oxidation of primary alcohols

Metals supported on metal oxides are common heterogeneous catalysts. Here the authors show that metal/oxide interfacial sites are highly active for alcohol oxidation—independent of the particle sizes—and use this information to design inverse oxide-on-metal particles with high activity and stability...

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Autores principales:	Guofeng Zhao, Fan Yang, Zongjia Chen, Qingfei Liu, Yongjun Ji, Yi Zhang, Zhiqiang Niu, Junjie Mao, Xinhe Bao, Peijun Hu, Yadong Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a355259177444ff4b0f5065f1fa1a55c
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spelling	oai:doaj.org-article:a355259177444ff4b0f5065f1fa1a55c2021-12-02T15:38:56ZMetal/oxide interfacial effects on the selective oxidation of primary alcohols10.1038/ncomms140392041-1723https://doaj.org/article/a355259177444ff4b0f5065f1fa1a55c2017-01-01T00:00:00Zhttps://doi.org/10.1038/ncomms14039https://doaj.org/toc/2041-1723Metals supported on metal oxides are common heterogeneous catalysts. Here the authors show that metal/oxide interfacial sites are highly active for alcohol oxidation—independent of the particle sizes—and use this information to design inverse oxide-on-metal particles with high activity and stability.Guofeng ZhaoFan YangZongjia ChenQingfei LiuYongjun JiYi ZhangZhiqiang NiuJunjie MaoXinhe BaoPeijun HuYadong LiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Guofeng Zhao Fan Yang Zongjia Chen Qingfei Liu Yongjun Ji Yi Zhang Zhiqiang Niu Junjie Mao Xinhe Bao Peijun Hu Yadong Li Metal/oxide interfacial effects on the selective oxidation of primary alcohols
description	Metals supported on metal oxides are common heterogeneous catalysts. Here the authors show that metal/oxide interfacial sites are highly active for alcohol oxidation—independent of the particle sizes—and use this information to design inverse oxide-on-metal particles with high activity and stability.
format	article
author	Guofeng Zhao Fan Yang Zongjia Chen Qingfei Liu Yongjun Ji Yi Zhang Zhiqiang Niu Junjie Mao Xinhe Bao Peijun Hu Yadong Li
author_facet	Guofeng Zhao Fan Yang Zongjia Chen Qingfei Liu Yongjun Ji Yi Zhang Zhiqiang Niu Junjie Mao Xinhe Bao Peijun Hu Yadong Li
author_sort	Guofeng Zhao
title	Metal/oxide interfacial effects on the selective oxidation of primary alcohols
title_short	Metal/oxide interfacial effects on the selective oxidation of primary alcohols
title_full	Metal/oxide interfacial effects on the selective oxidation of primary alcohols
title_fullStr	Metal/oxide interfacial effects on the selective oxidation of primary alcohols
title_full_unstemmed	Metal/oxide interfacial effects on the selective oxidation of primary alcohols
title_sort	metal/oxide interfacial effects on the selective oxidation of primary alcohols
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/a355259177444ff4b0f5065f1fa1a55c
work_keys_str_mv	AT guofengzhao metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT fanyang metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT zongjiachen metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT qingfeiliu metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT yongjunji metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT yizhang metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT zhiqiangniu metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT junjiemao metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT xinhebao metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT peijunhu metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols AT yadongli metaloxideinterfacialeffectsontheselectiveoxidationofprimaryalcohols
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Metal/oxide interfacial effects on the selective oxidation of primary alcohols

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