Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes

Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.

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Detalles Bibliográficos
Autores principales: Jiwei Wang, Xiaoming Cao, Shichang Lv, Caiyun Zhang, Sheng Xu, Min Shi, Jun Zhang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b8
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Sumario:Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.