Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes

Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.

Guardado en:
Detalles Bibliográficos
Autores principales: Jiwei Wang, Xiaoming Cao, Shichang Lv, Caiyun Zhang, Sheng Xu, Min Shi, Jun Zhang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
Materias:
Q
Acceso en línea:https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b8
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:a3941fd18c344357bf12ac9a0e0688b8
record_format dspace
spelling oai:doaj.org-article:a3941fd18c344357bf12ac9a0e0688b82021-12-02T15:38:33ZSynthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes10.1038/ncomms146252041-1723https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b82017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14625https://doaj.org/toc/2041-1723Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.Jiwei WangXiaoming CaoShichang LvCaiyun ZhangSheng XuMin ShiJun ZhangNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jiwei Wang
Xiaoming Cao
Shichang Lv
Caiyun Zhang
Sheng Xu
Min Shi
Jun Zhang
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
description Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.
format article
author Jiwei Wang
Xiaoming Cao
Shichang Lv
Caiyun Zhang
Sheng Xu
Min Shi
Jun Zhang
author_facet Jiwei Wang
Xiaoming Cao
Shichang Lv
Caiyun Zhang
Sheng Xu
Min Shi
Jun Zhang
author_sort Jiwei Wang
title Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
title_short Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
title_full Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
title_fullStr Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
title_full_unstemmed Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
title_sort synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b8
work_keys_str_mv AT jiweiwang synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT xiaomingcao synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT shichanglv synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT caiyunzhang synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT shengxu synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT minshi synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
AT junzhang synthesisandstructuresofgoldandcoppercarbeneintermediatesincatalyticaminationofalkynes
_version_ 1718386190488436736