Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.
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Nature Portfolio
2017
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oai:doaj.org-article:a3941fd18c344357bf12ac9a0e0688b82021-12-02T15:38:33ZSynthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes10.1038/ncomms146252041-1723https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b82017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14625https://doaj.org/toc/2041-1723Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions.Jiwei WangXiaoming CaoShichang LvCaiyun ZhangSheng XuMin ShiJun ZhangNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-10 (2017) |
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Science Q Jiwei Wang Xiaoming Cao Shichang Lv Caiyun Zhang Sheng Xu Min Shi Jun Zhang Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
description |
Metal carbenes are typically highly reactive and unstable species, proposed as intermediates in numerous catalytic processes. Here the authors report the isolation and characterization of gold and copper carbene intermediates involved in catalytic cyclization reactions. |
format |
article |
author |
Jiwei Wang Xiaoming Cao Shichang Lv Caiyun Zhang Sheng Xu Min Shi Jun Zhang |
author_facet |
Jiwei Wang Xiaoming Cao Shichang Lv Caiyun Zhang Sheng Xu Min Shi Jun Zhang |
author_sort |
Jiwei Wang |
title |
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
title_short |
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
title_full |
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
title_fullStr |
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
title_full_unstemmed |
Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
title_sort |
synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/a3941fd18c344357bf12ac9a0e0688b8 |
work_keys_str_mv |
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1718386190488436736 |