Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method

Abstract Zirconium phosphide (ZrP) powders were synthesized by elemental combination method via the direct reaction of zirconium powders with red phosphorus, and characterized by XRD, SEM, XPS, XRF, SAED and TEM measurements. The obtained ZrP powders were found to exhibit apparent activity in the re...

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Autores principales:	Zhen Li, Ning Chen, Jigang Wang, Peishen Li, Ming Guo, Qiang Wang, Chunhong Li, Changzheng Wang, Tao Guo, Shaowei Chen
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/a45d754449c74dc282cdf88612d3644d
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spelling	oai:doaj.org-article:a45d754449c74dc282cdf88612d3644d2021-12-02T15:06:27ZEfficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method10.1038/s41598-017-13616-52045-2322https://doaj.org/article/a45d754449c74dc282cdf88612d3644d2017-10-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-13616-5https://doaj.org/toc/2045-2322Abstract Zirconium phosphide (ZrP) powders were synthesized by elemental combination method via the direct reaction of zirconium powders with red phosphorus, and characterized by XRD, SEM, XPS, XRF, SAED and TEM measurements. The obtained ZrP powders were found to exhibit apparent activity in the ready eliminateion of nitric oxide (NO) via facile redox reactions, and the elimination dynamics was evaluated within the context of various important experimental parameters, such as reaction temperature and gas concentration. At a fixed amount of ZrP powders, an increasing amount of NO would be eliminated with increasing reaction temperature, and complete conversion of NO to N2 could be reached in the range of 700 to 800 °C. The addition of NH3 also facilitated NO elimination at a fixed reaction temperature. Furthermore, of the products of the elimination process, zirconia (ZrO2) powder is a kind of biocompatible material, red phosphorus can be used to produce safety matches, organophosphorous pesticide and phosphor bronze, and the produced N2 might be collected and used as a protective gas or be converted into liquid nitrogen for other purposes.Zhen LiNing ChenJigang WangPeishen LiMing GuoQiang WangChunhong LiChangzheng WangTao GuoShaowei ChenNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Zhen Li Ning Chen Jigang Wang Peishen Li Ming Guo Qiang Wang Chunhong Li Changzheng Wang Tao Guo Shaowei Chen Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
description	Abstract Zirconium phosphide (ZrP) powders were synthesized by elemental combination method via the direct reaction of zirconium powders with red phosphorus, and characterized by XRD, SEM, XPS, XRF, SAED and TEM measurements. The obtained ZrP powders were found to exhibit apparent activity in the ready eliminateion of nitric oxide (NO) via facile redox reactions, and the elimination dynamics was evaluated within the context of various important experimental parameters, such as reaction temperature and gas concentration. At a fixed amount of ZrP powders, an increasing amount of NO would be eliminated with increasing reaction temperature, and complete conversion of NO to N2 could be reached in the range of 700 to 800 °C. The addition of NH3 also facilitated NO elimination at a fixed reaction temperature. Furthermore, of the products of the elimination process, zirconia (ZrO2) powder is a kind of biocompatible material, red phosphorus can be used to produce safety matches, organophosphorous pesticide and phosphor bronze, and the produced N2 might be collected and used as a protective gas or be converted into liquid nitrogen for other purposes.
format	article
author	Zhen Li Ning Chen Jigang Wang Peishen Li Ming Guo Qiang Wang Chunhong Li Changzheng Wang Tao Guo Shaowei Chen
author_facet	Zhen Li Ning Chen Jigang Wang Peishen Li Ming Guo Qiang Wang Chunhong Li Changzheng Wang Tao Guo Shaowei Chen
author_sort	Zhen Li
title	Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
title_short	Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
title_full	Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
title_fullStr	Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
title_full_unstemmed	Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
title_sort	efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/a45d754449c74dc282cdf88612d3644d
work_keys_str_mv	AT zhenli efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT ningchen efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT jigangwang efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT peishenli efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT mingguo efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT qiangwang efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT chunhongli efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT changzhengwang efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT taoguo efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod AT shaoweichen efficientreductionofnitricoxideusingzirconiumphosphidepowderssynthesizedbyelementalcombinationmethod
_version_	1718388469852536832

Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method

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