Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation

A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with t...

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Autores principales: Jun Zhou, Bingyao Jiang, Yamato Fujihira, Zhengyu Zhao, Takanori Imai, Norio Shibata
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/a518b1524bb44d3fb2732d1225497e4f
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Sumario:A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with tertiary or quaternary carbon centres.