Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with t...
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| Autores principales: | , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/a518b1524bb44d3fb2732d1225497e4f |
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| Sumario: | A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with tertiary or quaternary carbon centres. |
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