Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation

A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with t...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Jun Zhou, Bingyao Jiang, Yamato Fujihira, Zhengyu Zhao, Takanori Imai, Norio Shibata
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a518b1524bb44d3fb2732d1225497e4f
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:a518b1524bb44d3fb2732d1225497e4f
record_format	dspace
spelling	oai:doaj.org-article:a518b1524bb44d3fb2732d1225497e4f2021-12-02T17:40:28ZCatalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation10.1038/s41467-021-24031-w2041-1723https://doaj.org/article/a518b1524bb44d3fb2732d1225497e4f2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24031-whttps://doaj.org/toc/2041-1723A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with tertiary or quaternary carbon centres.Jun ZhouBingyao JiangYamato FujihiraZhengyu ZhaoTakanori ImaiNorio ShibataNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jun Zhou Bingyao Jiang Yamato Fujihira Zhengyu Zhao Takanori Imai Norio Shibata Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
description	A regioselective carbosilylation of alkenes is a powerful strategy to access functionalized silylated alkanes. In this study, the authors report a catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides, mediated by t BuOK, and synthesise various silylated alkanes with tertiary or quaternary carbon centres.
format	article
author	Jun Zhou Bingyao Jiang Yamato Fujihira Zhengyu Zhao Takanori Imai Norio Shibata
author_facet	Jun Zhou Bingyao Jiang Yamato Fujihira Zhengyu Zhao Takanori Imai Norio Shibata
author_sort	Jun Zhou
title	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
title_short	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
title_full	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
title_fullStr	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
title_full_unstemmed	Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation
title_sort	catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective c-f bond activation
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/a518b1524bb44d3fb2732d1225497e4f
work_keys_str_mv	AT junzhou catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation AT bingyaojiang catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation AT yamatofujihira catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation AT zhengyuzhao catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation AT takanoriimai catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation AT norioshibata catalystfreecarbosilylationofalkenesusingsilylboronatesandorganicfluoridesviaselectivecfbondactivation
_version_	1718379780442685440

Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation

Ejemplares similares