Effective treatment of the wastewater from ceramic industry using ceramic membranes

Emissions of organic compounds, heavy metals and chemicals used in the ceramic industry cause significant organic and inorganic pollution of water. The effluent must be treated before it is discharged into a water body. International and EU laws control the chemical oxygen demand (COD) of the wastew...

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Autores principales: Maxim Shurygin, Christiane Guenther, Stephan Fuchs, Volker Prehn
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Publicado: IWA Publishing 2021
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spelling oai:doaj.org-article:a51a7d39cbae410aa50ba18d20828acd2021-11-06T10:50:44ZEffective treatment of the wastewater from ceramic industry using ceramic membranes0273-12231996-973210.2166/wst.2021.039https://doaj.org/article/a51a7d39cbae410aa50ba18d20828acd2021-03-01T00:00:00Zhttp://wst.iwaponline.com/content/83/5/1055https://doaj.org/toc/0273-1223https://doaj.org/toc/1996-9732Emissions of organic compounds, heavy metals and chemicals used in the ceramic industry cause significant organic and inorganic pollution of water. The effluent must be treated before it is discharged into a water body. International and EU laws control the chemical oxygen demand (COD) of the wastewater. Conventional technologies, such as sedimentation, flocculation and biological treatment, have lots of drawbacks, whereas membrane technologies give many benefits, as they are chemical-free and allow a reduction of the treatment steps. One-step wastewater nanofiltration with ceramic membranes of 450 Da cut-off is able to reduce the COD of ceramic wastewater to a sufficient level. However, the working time without cleaning is limited and the rejection of membranes can be significantly reduced due to fouling. Multistage filtration can be the solution. Filtration experiments with various combinations (MF, UF and NF) of ceramic membranes were performed at a laboratory scale with single-channel membranes and at pilot scale with 7-, 19- and 151-channel membranes in order to permanently reach the limit value of a COD below 80 mg/L and to increase the operating time. Four types of membranes were sequentially tested in the cross-flow mode: MF (200 nm pore size), UF (2,000 Da), NF (450 Da) and NF (200 Da). 5-day Biological Oxygen Demand (BOD) tests were performed in order to examine the wastewater biodegradability. The test results with single-channel membranes showed that in terms of the highest COD rejection and the highest permeability, the best combination was that of MF and UF membranes. Here, UF membranes were sufficient to reach the limit values. As for the multi-channel membranes, the combination of MF and NF (450 Da) was the best and the final COD concentration ranged from 11 to 48 mg/L. 5-day BOD bottle tests showed a COD/BOD ratio of 3.8, which opened up possibilities for combined treatment.Maxim ShuryginChristiane GuentherStephan FuchsVolker PrehnIWA Publishingarticleceramic membranesceramic wastewatermicrofiltrationmultistep filtrationnanofiltrationultrafiltrationEnvironmental technology. Sanitary engineeringTD1-1066ENWater Science and Technology, Vol 83, Iss 5, Pp 1055-1071 (2021)
institution DOAJ
collection DOAJ
language EN
topic ceramic membranes
ceramic wastewater
microfiltration
multistep filtration
nanofiltration
ultrafiltration
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle ceramic membranes
ceramic wastewater
microfiltration
multistep filtration
nanofiltration
ultrafiltration
Environmental technology. Sanitary engineering
TD1-1066
Maxim Shurygin
Christiane Guenther
Stephan Fuchs
Volker Prehn
Effective treatment of the wastewater from ceramic industry using ceramic membranes
description Emissions of organic compounds, heavy metals and chemicals used in the ceramic industry cause significant organic and inorganic pollution of water. The effluent must be treated before it is discharged into a water body. International and EU laws control the chemical oxygen demand (COD) of the wastewater. Conventional technologies, such as sedimentation, flocculation and biological treatment, have lots of drawbacks, whereas membrane technologies give many benefits, as they are chemical-free and allow a reduction of the treatment steps. One-step wastewater nanofiltration with ceramic membranes of 450 Da cut-off is able to reduce the COD of ceramic wastewater to a sufficient level. However, the working time without cleaning is limited and the rejection of membranes can be significantly reduced due to fouling. Multistage filtration can be the solution. Filtration experiments with various combinations (MF, UF and NF) of ceramic membranes were performed at a laboratory scale with single-channel membranes and at pilot scale with 7-, 19- and 151-channel membranes in order to permanently reach the limit value of a COD below 80 mg/L and to increase the operating time. Four types of membranes were sequentially tested in the cross-flow mode: MF (200 nm pore size), UF (2,000 Da), NF (450 Da) and NF (200 Da). 5-day Biological Oxygen Demand (BOD) tests were performed in order to examine the wastewater biodegradability. The test results with single-channel membranes showed that in terms of the highest COD rejection and the highest permeability, the best combination was that of MF and UF membranes. Here, UF membranes were sufficient to reach the limit values. As for the multi-channel membranes, the combination of MF and NF (450 Da) was the best and the final COD concentration ranged from 11 to 48 mg/L. 5-day BOD bottle tests showed a COD/BOD ratio of 3.8, which opened up possibilities for combined treatment.
format article
author Maxim Shurygin
Christiane Guenther
Stephan Fuchs
Volker Prehn
author_facet Maxim Shurygin
Christiane Guenther
Stephan Fuchs
Volker Prehn
author_sort Maxim Shurygin
title Effective treatment of the wastewater from ceramic industry using ceramic membranes
title_short Effective treatment of the wastewater from ceramic industry using ceramic membranes
title_full Effective treatment of the wastewater from ceramic industry using ceramic membranes
title_fullStr Effective treatment of the wastewater from ceramic industry using ceramic membranes
title_full_unstemmed Effective treatment of the wastewater from ceramic industry using ceramic membranes
title_sort effective treatment of the wastewater from ceramic industry using ceramic membranes
publisher IWA Publishing
publishDate 2021
url https://doaj.org/article/a51a7d39cbae410aa50ba18d20828acd
work_keys_str_mv AT maximshurygin effectivetreatmentofthewastewaterfromceramicindustryusingceramicmembranes
AT christianeguenther effectivetreatmentofthewastewaterfromceramicindustryusingceramicmembranes
AT stephanfuchs effectivetreatmentofthewastewaterfromceramicindustryusingceramicmembranes
AT volkerprehn effectivetreatmentofthewastewaterfromceramicindustryusingceramicmembranes
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