Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis

Hydrogen atom transfer (HAT) hydrogenation of alkenes usually requires stoichiometric silanes and peroxides. Here, the authors report a silane- and peroxide-free HAT hydrogenation method using a combined cobalt/photoredox catalysis and vitamin C as a sole stoichiometric reactant.

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Autores principales:	Yuji Kamei, Yusuke Seino, Yuto Yamaguchi, Tatsuhiko Yoshino, Satoshi Maeda, Masahiro Kojima, Shigeki Matsunaga
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a56081321b4f461bbcb59287a5d99175
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spelling	oai:doaj.org-article:a56081321b4f461bbcb59287a5d991752021-12-02T14:26:52ZSilane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis10.1038/s41467-020-20872-z2041-1723https://doaj.org/article/a56081321b4f461bbcb59287a5d991752021-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20872-zhttps://doaj.org/toc/2041-1723Hydrogen atom transfer (HAT) hydrogenation of alkenes usually requires stoichiometric silanes and peroxides. Here, the authors report a silane- and peroxide-free HAT hydrogenation method using a combined cobalt/photoredox catalysis and vitamin C as a sole stoichiometric reactant.Yuji KameiYusuke SeinoYuto YamaguchiTatsuhiko YoshinoSatoshi MaedaMasahiro KojimaShigeki MatsunagaNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yuji Kamei Yusuke Seino Yuto Yamaguchi Tatsuhiko Yoshino Satoshi Maeda Masahiro Kojima Shigeki Matsunaga Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
description	Hydrogen atom transfer (HAT) hydrogenation of alkenes usually requires stoichiometric silanes and peroxides. Here, the authors report a silane- and peroxide-free HAT hydrogenation method using a combined cobalt/photoredox catalysis and vitamin C as a sole stoichiometric reactant.
format	article
author	Yuji Kamei Yusuke Seino Yuto Yamaguchi Tatsuhiko Yoshino Satoshi Maeda Masahiro Kojima Shigeki Matsunaga
author_facet	Yuji Kamei Yusuke Seino Yuto Yamaguchi Tatsuhiko Yoshino Satoshi Maeda Masahiro Kojima Shigeki Matsunaga
author_sort	Yuji Kamei
title	Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
title_short	Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
title_full	Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
title_fullStr	Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
title_full_unstemmed	Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
title_sort	silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/a56081321b4f461bbcb59287a5d99175
work_keys_str_mv	AT yujikamei silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT yusukeseino silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT yutoyamaguchi silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT tatsuhikoyoshino silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT satoshimaeda silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT masahirokojima silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis AT shigekimatsunaga silaneandperoxidefreehydrogenatomtransferhydrogenationusingascorbicacidandcobaltphotoredoxdualcatalysis
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Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis

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