Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers

The reactivity of expanded porphyrins is highly influenced by their scaffold architecture. Here, the authors construct two nonaromatic dumbbell-shaped benzene- and pyridine-incorporating octaphyrins via Suzuki-Miyaura cross-coupling; depending on the framework, different coordination modes are obtai...

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Autores principales:	Le Liu, Zhiwen Hu, Fenni Zhang, Yang Liu, Ling Xu, Mingbo Zhou, Takayuki Tanaka, Atsuhiro Osuka, Jianxin Song
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a59ad4f2646f41c9b0155003fb2a9e21
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id	oai:doaj.org-article:a59ad4f2646f41c9b0155003fb2a9e21
record_format	dspace
spelling	oai:doaj.org-article:a59ad4f2646f41c9b0155003fb2a9e212021-12-02T16:56:32ZBenzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers10.1038/s41467-020-20072-92041-1723https://doaj.org/article/a59ad4f2646f41c9b0155003fb2a9e212020-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20072-9https://doaj.org/toc/2041-1723The reactivity of expanded porphyrins is highly influenced by their scaffold architecture. Here, the authors construct two nonaromatic dumbbell-shaped benzene- and pyridine-incorporating octaphyrins via Suzuki-Miyaura cross-coupling; depending on the framework, different coordination modes are obtained upon metallation with Pd(II).Le LiuZhiwen HuFenni ZhangYang LiuLing XuMingbo ZhouTakayuki TanakaAtsuhiro OsukaJianxin SongNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Le Liu Zhiwen Hu Fenni Zhang Yang Liu Ling Xu Mingbo Zhou Takayuki Tanaka Atsuhiro Osuka Jianxin Song Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
description	The reactivity of expanded porphyrins is highly influenced by their scaffold architecture. Here, the authors construct two nonaromatic dumbbell-shaped benzene- and pyridine-incorporating octaphyrins via Suzuki-Miyaura cross-coupling; depending on the framework, different coordination modes are obtained upon metallation with Pd(II).
format	article
author	Le Liu Zhiwen Hu Fenni Zhang Yang Liu Ling Xu Mingbo Zhou Takayuki Tanaka Atsuhiro Osuka Jianxin Song
author_facet	Le Liu Zhiwen Hu Fenni Zhang Yang Liu Ling Xu Mingbo Zhou Takayuki Tanaka Atsuhiro Osuka Jianxin Song
author_sort	Le Liu
title	Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
title_short	Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
title_full	Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
title_fullStr	Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
title_full_unstemmed	Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers
title_sort	benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two pdii centers
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/a59ad4f2646f41c9b0155003fb2a9e21
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Benzene- and pyridine-incorporated octaphyrins with different coordination modes toward two PdII centers

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