Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds

Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds

C-N bond forming is an established strategy to form amines, which are quintessential in chemical synthesis and in nature. Here, the authors report three classes of photoredox reactions, involving C(sp3)-N coupling between N-centered radicals and alkyl radicals and C(sp3)- C(sp3) coupling via C(sp3)-...

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Autores principales: Quanping Guo, Qiang Peng, Hongli Chai, Yumei Huo, Shan Wang, Zhaoqing Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/a5e28aeb4fb844c9ba1da8335ee1366e
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spelling oai:doaj.org-article:a5e28aeb4fb844c9ba1da8335ee1366e2021-12-02T17:32:26ZVisible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds10.1038/s41467-020-15167-22041-1723https://doaj.org/article/a5e28aeb4fb844c9ba1da8335ee1366e2020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15167-2https://doaj.org/toc/2041-1723C-N bond forming is an established strategy to form amines, which are quintessential in chemical synthesis and in nature. Here, the authors report three classes of photoredox reactions, involving C(sp3)-N coupling between N-centered radicals and alkyl radicals and C(sp3)- C(sp3) coupling via C(sp3)-H alkylation.Quanping GuoQiang PengHongli ChaiYumei HuoShan WangZhaoqing XuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Quanping Guo
Qiang Peng
Hongli Chai
Yumei Huo
Shan Wang
Zhaoqing Xu
Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
description C-N bond forming is an established strategy to form amines, which are quintessential in chemical synthesis and in nature. Here, the authors report three classes of photoredox reactions, involving C(sp3)-N coupling between N-centered radicals and alkyl radicals and C(sp3)- C(sp3) coupling via C(sp3)-H alkylation.
format article
author Quanping Guo
Qiang Peng
Hongli Chai
Yumei Huo
Shan Wang
Zhaoqing Xu
author_facet Quanping Guo
Qiang Peng
Hongli Chai
Yumei Huo
Shan Wang
Zhaoqing Xu
author_sort Quanping Guo
title Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
title_short Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
title_full Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
title_fullStr Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
title_full_unstemmed Visible-light promoted regioselective amination and alkylation of remote C(sp3)-H bonds
title_sort visible-light promoted regioselective amination and alkylation of remote c(sp3)-h bonds
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/a5e28aeb4fb844c9ba1da8335ee1366e
work_keys_str_mv AT quanpingguo visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
AT qiangpeng visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
AT honglichai visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
AT yumeihuo visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
AT shanwang visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
AT zhaoqingxu visiblelightpromotedregioselectiveaminationandalkylationofremotecsp3hbonds
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