Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices

High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during...

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Autores principales: Cheng Zhu, André K. Eckhardt, Sankhabrata Chandra, Andrew M. Turner, Peter R. Schreiner, Ralf I. Kaiser
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/a5e7465c29c14f928b298e9573656eb7
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Sumario:High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during sublimation of PH3 and N2 ice mixtures exposed to energetic electrons.