Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices
High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during...
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Nature Portfolio
2021
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oai:doaj.org-article:a5e7465c29c14f928b298e9573656eb72021-12-02T15:31:37ZIdentification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices10.1038/s41467-021-25775-12041-1723https://doaj.org/article/a5e7465c29c14f928b298e9573656eb72021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25775-1https://doaj.org/toc/2041-1723High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during sublimation of PH3 and N2 ice mixtures exposed to energetic electrons.Cheng ZhuAndré K. EckhardtSankhabrata ChandraAndrew M. TurnerPeter R. SchreinerRalf I. KaiserNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021) |
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Science Q Cheng Zhu André K. Eckhardt Sankhabrata Chandra Andrew M. Turner Peter R. Schreiner Ralf I. Kaiser Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
description |
High-nitrogen content polyhedral molecules are of fundamental interest for theory and for synthesis applications. The authors, using isomer selective, tunable soft photoionization reflectron time-of-flight mass spectrometry, identify the formation of a hitherto elusive prismatic P3N3 molecule during sublimation of PH3 and N2 ice mixtures exposed to energetic electrons. |
format |
article |
author |
Cheng Zhu André K. Eckhardt Sankhabrata Chandra Andrew M. Turner Peter R. Schreiner Ralf I. Kaiser |
author_facet |
Cheng Zhu André K. Eckhardt Sankhabrata Chandra Andrew M. Turner Peter R. Schreiner Ralf I. Kaiser |
author_sort |
Cheng Zhu |
title |
Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
title_short |
Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
title_full |
Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
title_fullStr |
Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
title_full_unstemmed |
Identification of a prismatic P3N3 molecule formed from electron irradiated phosphine-nitrogen ices |
title_sort |
identification of a prismatic p3n3 molecule formed from electron irradiated phosphine-nitrogen ices |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/a5e7465c29c14f928b298e9573656eb7 |
work_keys_str_mv |
AT chengzhu identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices AT andrekeckhardt identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices AT sankhabratachandra identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices AT andrewmturner identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices AT peterrschreiner identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices AT ralfikaiser identificationofaprismaticp3n3moleculeformedfromelectronirradiatedphosphinenitrogenices |
_version_ |
1718387159871782912 |