3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks

Here we report new porous carbon materials obtained by 3D printing from photopolymer compositions with zinc- and nickel-based metal–organic frameworks, ZIF-8 and Ni-BTC, followed by high-temperature pyrolysis. The pyrolyzed materials that retain the shapes of complex objects contain pores, which wer...

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Autores principales:	Anton I. Cherevko, Igor A. Nikovskiy, Yulia V. Nelyubina, Kirill M. Skupov, Nikolay N. Efimov, Valentin V. Novikov
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	3D printing composite materials metal–organic frameworks photopolymer porous carbon materials pyrolysis Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/a6575195a82442d6b90c4e647fe55aed
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spelling	oai:doaj.org-article:a6575195a82442d6b90c4e647fe55aed2021-11-25T18:47:55Z3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks10.3390/polym132238812073-4360https://doaj.org/article/a6575195a82442d6b90c4e647fe55aed2021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3881https://doaj.org/toc/2073-4360Here we report new porous carbon materials obtained by 3D printing from photopolymer compositions with zinc- and nickel-based metal–organic frameworks, ZIF-8 and Ni-BTC, followed by high-temperature pyrolysis. The pyrolyzed materials that retain the shapes of complex objects contain pores, which were produced by boiling zinc and magnetic nickel particles. The two thus provided functionalities—large specific surface area and ferromagnetism—that pave the way towards creating heterogenous catalysts that can be easily removed from reaction mixtures in industrial catalytic processes.Anton I. CherevkoIgor A. NikovskiyYulia V. NelyubinaKirill M. SkupovNikolay N. EfimovValentin V. NovikovMDPI AGarticle3D printingcomposite materialsmetal–organic frameworksphotopolymerporous carbon materialspyrolysisOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3881, p 3881 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	3D printing composite materials metal–organic frameworks photopolymer porous carbon materials pyrolysis Organic chemistry QD241-441
spellingShingle	3D printing composite materials metal–organic frameworks photopolymer porous carbon materials pyrolysis Organic chemistry QD241-441 Anton I. Cherevko Igor A. Nikovskiy Yulia V. Nelyubina Kirill M. Skupov Nikolay N. Efimov Valentin V. Novikov 3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
description	Here we report new porous carbon materials obtained by 3D printing from photopolymer compositions with zinc- and nickel-based metal–organic frameworks, ZIF-8 and Ni-BTC, followed by high-temperature pyrolysis. The pyrolyzed materials that retain the shapes of complex objects contain pores, which were produced by boiling zinc and magnetic nickel particles. The two thus provided functionalities—large specific surface area and ferromagnetism—that pave the way towards creating heterogenous catalysts that can be easily removed from reaction mixtures in industrial catalytic processes.
format	article
author	Anton I. Cherevko Igor A. Nikovskiy Yulia V. Nelyubina Kirill M. Skupov Nikolay N. Efimov Valentin V. Novikov
author_facet	Anton I. Cherevko Igor A. Nikovskiy Yulia V. Nelyubina Kirill M. Skupov Nikolay N. Efimov Valentin V. Novikov
author_sort	Anton I. Cherevko
title	3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
title_short	3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
title_full	3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
title_fullStr	3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
title_full_unstemmed	3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks
title_sort	3d-printed porous magnetic carbon materials derived from metal–organic frameworks
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/a6575195a82442d6b90c4e647fe55aed
work_keys_str_mv	AT antonicherevko 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks AT igoranikovskiy 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks AT yuliavnelyubina 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks AT kirillmskupov 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks AT nikolaynefimov 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks AT valentinvnovikov 3dprintedporousmagneticcarbonmaterialsderivedfrommetalorganicframeworks
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3D-Printed Porous Magnetic Carbon Materials Derived from Metal–Organic Frameworks

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