Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state

Preparation of cyclobutanes with four different substituents is rare and often arduous. Here a cocrystallisation strategy enables the intermolecular [2+2] cross-photoreaction of non-symmetrical stilbene derivatives to obtain chiral tetrasubstituted cyclobutanes with up to four different substituents...

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Autores principales:	Michael A. Sinnwell, Ryan H. Groeneman, Benjamin J. Ingenthron, Changan Li, Leonard R. MacGillivray
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/a6ea5b35ee29422d87485a9e4518e741
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spelling	oai:doaj.org-article:a6ea5b35ee29422d87485a9e4518e7412021-12-02T16:57:12ZSupramolecular construction of a cyclobutane ring system with four different substituents in the solid state10.1038/s42004-021-00493-32399-3669https://doaj.org/article/a6ea5b35ee29422d87485a9e4518e7412021-05-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00493-3https://doaj.org/toc/2399-3669Preparation of cyclobutanes with four different substituents is rare and often arduous. Here a cocrystallisation strategy enables the intermolecular [2+2] cross-photoreaction of non-symmetrical stilbene derivatives to obtain chiral tetrasubstituted cyclobutanes with up to four different substituents in quantitative yield.Michael A. SinnwellRyan H. GroenemanBenjamin J. IngenthronChangan LiLeonard R. MacGillivrayNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Michael A. Sinnwell Ryan H. Groeneman Benjamin J. Ingenthron Changan Li Leonard R. MacGillivray Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
description	Preparation of cyclobutanes with four different substituents is rare and often arduous. Here a cocrystallisation strategy enables the intermolecular [2+2] cross-photoreaction of non-symmetrical stilbene derivatives to obtain chiral tetrasubstituted cyclobutanes with up to four different substituents in quantitative yield.
format	article
author	Michael A. Sinnwell Ryan H. Groeneman Benjamin J. Ingenthron Changan Li Leonard R. MacGillivray
author_facet	Michael A. Sinnwell Ryan H. Groeneman Benjamin J. Ingenthron Changan Li Leonard R. MacGillivray
author_sort	Michael A. Sinnwell
title	Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
title_short	Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
title_full	Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
title_fullStr	Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
title_full_unstemmed	Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
title_sort	supramolecular construction of a cyclobutane ring system with four different substituents in the solid state
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/a6ea5b35ee29422d87485a9e4518e741
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Supramolecular construction of a cyclobutane ring system with four different substituents in the solid state

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