Direct deoxygenative borylation of carboxylic acids

Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carbo...

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Autores principales: Jianbin Li, Chia-Yu Huang, Mohamad Ataya, Rustam Z. Khaliullin, Chao-Jun Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace295
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Sumario:Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carboxylic acids.