Direct deoxygenative borylation of carboxylic acids

Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carbo...

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Autores principales: Jianbin Li, Chia-Yu Huang, Mohamad Ataya, Rustam Z. Khaliullin, Chao-Jun Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace295
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spelling oai:doaj.org-article:a6f4905c22944a00aa2c69ecf7ace2952021-12-02T17:08:39ZDirect deoxygenative borylation of carboxylic acids10.1038/s41467-021-25229-82041-1723https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace2952021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25229-8https://doaj.org/toc/2041-1723Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carboxylic acids.Jianbin LiChia-Yu HuangMohamad AtayaRustam Z. KhaliullinChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jianbin Li
Chia-Yu Huang
Mohamad Ataya
Rustam Z. Khaliullin
Chao-Jun Li
Direct deoxygenative borylation of carboxylic acids
description Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carboxylic acids.
format article
author Jianbin Li
Chia-Yu Huang
Mohamad Ataya
Rustam Z. Khaliullin
Chao-Jun Li
author_facet Jianbin Li
Chia-Yu Huang
Mohamad Ataya
Rustam Z. Khaliullin
Chao-Jun Li
author_sort Jianbin Li
title Direct deoxygenative borylation of carboxylic acids
title_short Direct deoxygenative borylation of carboxylic acids
title_full Direct deoxygenative borylation of carboxylic acids
title_fullStr Direct deoxygenative borylation of carboxylic acids
title_full_unstemmed Direct deoxygenative borylation of carboxylic acids
title_sort direct deoxygenative borylation of carboxylic acids
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace295
work_keys_str_mv AT jianbinli directdeoxygenativeborylationofcarboxylicacids
AT chiayuhuang directdeoxygenativeborylationofcarboxylicacids
AT mohamadataya directdeoxygenativeborylationofcarboxylicacids
AT rustamzkhaliullin directdeoxygenativeborylationofcarboxylicacids
AT chaojunli directdeoxygenativeborylationofcarboxylicacids
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