Direct deoxygenative borylation of carboxylic acids
Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carbo...
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Nature Portfolio
2021
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oai:doaj.org-article:a6f4905c22944a00aa2c69ecf7ace2952021-12-02T17:08:39ZDirect deoxygenative borylation of carboxylic acids10.1038/s41467-021-25229-82041-1723https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace2952021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25229-8https://doaj.org/toc/2041-1723Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carboxylic acids.Jianbin LiChia-Yu HuangMohamad AtayaRustam Z. KhaliullinChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021) |
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Science Q Jianbin Li Chia-Yu Huang Mohamad Ataya Rustam Z. Khaliullin Chao-Jun Li Direct deoxygenative borylation of carboxylic acids |
description |
Converting a carboxylic acid into a boronic acid, which makes a useful chemical handle from a feedstock chemical, currently relies on decarboxylation and requires metal catalysts and prior functionalization. Here the authors show a simplified procedure via deoxygenation, using diboron and free carboxylic acids. |
format |
article |
author |
Jianbin Li Chia-Yu Huang Mohamad Ataya Rustam Z. Khaliullin Chao-Jun Li |
author_facet |
Jianbin Li Chia-Yu Huang Mohamad Ataya Rustam Z. Khaliullin Chao-Jun Li |
author_sort |
Jianbin Li |
title |
Direct deoxygenative borylation of carboxylic acids |
title_short |
Direct deoxygenative borylation of carboxylic acids |
title_full |
Direct deoxygenative borylation of carboxylic acids |
title_fullStr |
Direct deoxygenative borylation of carboxylic acids |
title_full_unstemmed |
Direct deoxygenative borylation of carboxylic acids |
title_sort |
direct deoxygenative borylation of carboxylic acids |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/a6f4905c22944a00aa2c69ecf7ace295 |
work_keys_str_mv |
AT jianbinli directdeoxygenativeborylationofcarboxylicacids AT chiayuhuang directdeoxygenativeborylationofcarboxylicacids AT mohamadataya directdeoxygenativeborylationofcarboxylicacids AT rustamzkhaliullin directdeoxygenativeborylationofcarboxylicacids AT chaojunli directdeoxygenativeborylationofcarboxylicacids |
_version_ |
1718381515551801344 |