Identifying Eigen-like hydrated protons at negatively charged interfaces

Hydrated protons are always present in aqueous solution, but their molecular structure remains under debate. Here the authors use vibrational sum frequency spectroscopy to show that at negatively charged liquid–vapor interfaces, protons adopt a specific configuration characteristic of Eigen-like spe...

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Autores principales: Eric Tyrode, Sanghamitra Sengupta, Adrien Sthoer
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/a71c4a3ccfad43bc86021378d577ae9b
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spelling oai:doaj.org-article:a71c4a3ccfad43bc86021378d577ae9b2021-12-02T17:33:14ZIdentifying Eigen-like hydrated protons at negatively charged interfaces10.1038/s41467-020-14370-52041-1723https://doaj.org/article/a71c4a3ccfad43bc86021378d577ae9b2020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-14370-5https://doaj.org/toc/2041-1723Hydrated protons are always present in aqueous solution, but their molecular structure remains under debate. Here the authors use vibrational sum frequency spectroscopy to show that at negatively charged liquid–vapor interfaces, protons adopt a specific configuration characteristic of Eigen-like species.Eric TyrodeSanghamitra SenguptaAdrien SthoerNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Eric Tyrode
Sanghamitra Sengupta
Adrien Sthoer
Identifying Eigen-like hydrated protons at negatively charged interfaces
description Hydrated protons are always present in aqueous solution, but their molecular structure remains under debate. Here the authors use vibrational sum frequency spectroscopy to show that at negatively charged liquid–vapor interfaces, protons adopt a specific configuration characteristic of Eigen-like species.
format article
author Eric Tyrode
Sanghamitra Sengupta
Adrien Sthoer
author_facet Eric Tyrode
Sanghamitra Sengupta
Adrien Sthoer
author_sort Eric Tyrode
title Identifying Eigen-like hydrated protons at negatively charged interfaces
title_short Identifying Eigen-like hydrated protons at negatively charged interfaces
title_full Identifying Eigen-like hydrated protons at negatively charged interfaces
title_fullStr Identifying Eigen-like hydrated protons at negatively charged interfaces
title_full_unstemmed Identifying Eigen-like hydrated protons at negatively charged interfaces
title_sort identifying eigen-like hydrated protons at negatively charged interfaces
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/a71c4a3ccfad43bc86021378d577ae9b
work_keys_str_mv AT erictyrode identifyingeigenlikehydratedprotonsatnegativelychargedinterfaces
AT sanghamitrasengupta identifyingeigenlikehydratedprotonsatnegativelychargedinterfaces
AT adriensthoer identifyingeigenlikehydratedprotonsatnegativelychargedinterfaces
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