Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide

The capacitance spectra of the interdigital Pt–glassy As2Te13Ge8S3–Pt structures have been investigated in a range of 5–106 Hz with respect to temperature effects in both dry air and its mixture with a controlled concentration of nitrogen dioxide. It has been found that a decrease in the frequency o...

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Autor principal: Ciobanu, Marina
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Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2017
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spelling oai:doaj.org-article:a78cedb4e9bc44de826df8253dccf6ed2021-11-21T11:56:53ZFeatures of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide539.213.22537-63651810-648Xhttps://doaj.org/article/a78cedb4e9bc44de826df8253dccf6ed2017-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2017/article/71494https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365The capacitance spectra of the interdigital Pt–glassy As2Te13Ge8S3–Pt structures have been investigated in a range of 5–106 Hz with respect to temperature effects in both dry air and its mixture with a controlled concentration of nitrogen dioxide. It has been found that a decrease in the frequency of applied voltage to 103 Hz results in a rapid increase in the capacitance by several orders of magnitude. Environmental conditions dramatically influence the capacitance at low frequencies and, together with temperature regime, control the capacitance spectra and current–voltage characteristics of the films. The results are explained in terms of formation of a Schottky–Mott barrier that controls the properties of the contact junction. The contact-free part of the chalcogenide film surface, being more conducting than the bulk, acts as a capacitor, which can be controlled by interaction with gaseous species from the environment.Ciobanu, MarinaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 16, Iss 3-4, Pp 234-241 (2017)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Ciobanu, Marina
Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
description The capacitance spectra of the interdigital Pt–glassy As2Te13Ge8S3–Pt structures have been investigated in a range of 5–106 Hz with respect to temperature effects in both dry air and its mixture with a controlled concentration of nitrogen dioxide. It has been found that a decrease in the frequency of applied voltage to 103 Hz results in a rapid increase in the capacitance by several orders of magnitude. Environmental conditions dramatically influence the capacitance at low frequencies and, together with temperature regime, control the capacitance spectra and current–voltage characteristics of the films. The results are explained in terms of formation of a Schottky–Mott barrier that controls the properties of the contact junction. The contact-free part of the chalcogenide film surface, being more conducting than the bulk, acts as a capacitor, which can be controlled by interaction with gaseous species from the environment.
format article
author Ciobanu, Marina
author_facet Ciobanu, Marina
author_sort Ciobanu, Marina
title Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
title_short Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
title_full Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
title_fullStr Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
title_full_unstemmed Features of contact and surface processes in glassy As2Te13Ge8S3-based structures with Pt electrodes upon interaction with nitrogen dioxide
title_sort features of contact and surface processes in glassy as2te13ge8s3-based structures with pt electrodes upon interaction with nitrogen dioxide
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2017
url https://doaj.org/article/a78cedb4e9bc44de826df8253dccf6ed
work_keys_str_mv AT ciobanumarina featuresofcontactandsurfaceprocessesinglassyas2te13ge8s3basedstructureswithptelectrodesuponinteractionwithnitrogendioxide
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