Molybdenum impregnated g-C3N4 nanotubes as potentially active photocatalyst for renewable energy applications
Abstract Molybdenum (Mo) impregnated g-C3N4 (Mo-CN) nanotubes are fabricated via a thermal/hydrothermal process to augment photoelectrochemical properties during solar-driven water-splitting (SDWS) reactions. Graphitic-C3N4 is an attractive material for photocatalysis because of its suitable band en...
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| Autores principales: | , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/a7cb171a9bc84670a09c9f281f923155 |
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| Sumario: | Abstract Molybdenum (Mo) impregnated g-C3N4 (Mo-CN) nanotubes are fabricated via a thermal/hydrothermal process to augment photoelectrochemical properties during solar-driven water-splitting (SDWS) reactions. Graphitic-C3N4 is an attractive material for photocatalysis because of its suitable band energy, high thermal and chemical stability. The FE-SEM and HR-TEM comprehend the nanotube-like morphology of Mo-CN. The spectroscopic characterization revealed bandgap energy of 2.63 eV with high visible-light activity. The x-ray diffraction of pristine g-C3N4 and Mo-CN nanotubes discloses the formation of triazine-based nanocrystalline g-C3N4, which remains stable during hydrothermal impregnation of Mo. Furthermore, Mo-CN nanotubes possess high sp2-hybridized nitrogen content, and metallic/oxidized Mo nanoparticles (in a ratio of 1:2) are impregnated into g-C3N4. The XPS analysis confirms C, N, and Mo for known atomic and oxidation states in Mo-CN. Furthermore, high photocurrent efficiency (~ 5.5 mA/cm2) is observed from 5%-Mo-CN nanotubes. That displays efficient SDWS by 5%-Mo-CN nanotubes than other counterparts. Impedance spectroscopy illustrated the lowest charge transfer resistance (R ct ) of 5%-Mo-CN nanotubes, which further confirms the fast electron transfer kinetics and efficient charge separation resulting in high photocurrent generation. Hence, 5%Mo-CN composite nanotubes can serve as a potential photocatalytic material for viable solar-driven water splitting. |
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