Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide

This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization...

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Autores principales:	Odularu Ayodele T., Ajibade Peter A., Oyedeji Opeoluwa O., Mbese Johannes Z., Puschmann Horst
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	thiourea dimethylformamide crystal structure monoclinic Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/a804d8820b08454fbe23b7ff16d022a8
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spelling	oai:doaj.org-article:a804d8820b08454fbe23b7ff16d022a82021-12-05T14:10:43ZSynthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide2391-542010.1515/chem-2020-0061https://doaj.org/article/a804d8820b08454fbe23b7ff16d022a82021-05-01T00:00:00Zhttps://doi.org/10.1515/chem-2020-0061https://doaj.org/toc/2391-5420This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization under mild condition. Important classical N–H⋯O links the two molecules together. Results revealed that C16H17Cl2N3OS crystallized in the monoclinic space group P21/c with the respective cell parameters of a = 92,360 (4) Å, b = 7.2232 (3) Å, 25.2555 (11) Å, β = 91.376 (3), α = γ = 90°, V = 1684.40 (12) Å3, T = 119.94 (13) K and Z = 4 and Z′ = 1.Odularu Ayodele T.Ajibade Peter A.Oyedeji Opeoluwa O.Mbese Johannes Z.Puschmann HorstDe Gruyterarticlethioureadimethylformamidecrystal structuremonoclinicChemistryQD1-999ENOpen Chemistry, Vol 19, Iss 1, Pp 511-517 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	thiourea dimethylformamide crystal structure monoclinic Chemistry QD1-999
spellingShingle	thiourea dimethylformamide crystal structure monoclinic Chemistry QD1-999 Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
description	This study is about the synthesis of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide (C16H17Cl2N3OS) compound. Single crystals of the compound were obtained by slow evaporation of N,N′-bis(4-chlorophenyl)thiourea (C13H10Cl2N2S) in N,N-dimethylformamide (C3H7NO; DMF) through recrystallization under mild condition. Important classical N–H⋯O links the two molecules together. Results revealed that C16H17Cl2N3OS crystallized in the monoclinic space group P21/c with the respective cell parameters of a = 92,360 (4) Å, b = 7.2232 (3) Å, 25.2555 (11) Å, β = 91.376 (3), α = γ = 90°, V = 1684.40 (12) Å3, T = 119.94 (13) K and Z = 4 and Z′ = 1.
format	article
author	Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst
author_facet	Odularu Ayodele T. Ajibade Peter A. Oyedeji Opeoluwa O. Mbese Johannes Z. Puschmann Horst
author_sort	Odularu Ayodele T.
title	Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
title_short	Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
title_full	Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
title_fullStr	Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
title_full_unstemmed	Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
title_sort	synthesis and crystal structure of n,n′-bis(4-chlorophenyl)thiourea n,n-dimethylformamide
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/a804d8820b08454fbe23b7ff16d022a8
work_keys_str_mv	AT odularuayodelet synthesisandcrystalstructureofnnbis4chlorophenylthioureanndimethylformamide AT ajibadepetera synthesisandcrystalstructureofnnbis4chlorophenylthioureanndimethylformamide AT oyedejiopeoluwao synthesisandcrystalstructureofnnbis4chlorophenylthioureanndimethylformamide AT mbesejohannesz synthesisandcrystalstructureofnnbis4chlorophenylthioureanndimethylformamide AT puschmannhorst synthesisandcrystalstructureofnnbis4chlorophenylthioureanndimethylformamide
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Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide

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