Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica

Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>...

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Autores principales: Lung-Chien Chen, Li-Wei Chao, Chen-Yu Xu, Chih-Hung Hsu, Yi-Ting Lee, Zi-Min Xu, Chun-Cheng Lin, Zong-Liang Tseng
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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NIR
Acceso en línea:https://doaj.org/article/a8613f24f95b4dc89c0e4e40b8d220bb
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Sumario:Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> (FAPbI<sub>3</sub>) PNPs in silica protective layer at room temperature (approximately 26 °C) employing (3-aminopropyl) triethoxysilane (APTES). The resulting perovskite nanocomposite (PNCs) achieved a high photoluminescence (PL) quantum yield of 58.0% and good stability under atmospheric moisture conditions. Moreover, the PNCs showed high PL intensity over 1 month of storage (approximately 26 °C) and more than 380 min of PNCs solutions in DI water. The studied near-infrared (NIR) light-emitting diode (LED) combined a NIR-emitting PNCs coating and a blue InGaN-based chip that exhibited a 788 nm electroluminescence spectrum of NIR-LEDs under 2.6 V. This may be a powerful tool to track of muscle and disabled patients in the detection of a blood vessel.