Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica

Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>...

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Autores principales: Lung-Chien Chen, Li-Wei Chao, Chen-Yu Xu, Chih-Hung Hsu, Yi-Ting Lee, Zi-Min Xu, Chun-Cheng Lin, Zong-Liang Tseng
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:a8613f24f95b4dc89c0e4e40b8d220bb2021-11-25T16:55:24ZRoom-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica10.3390/bios111104402079-6374https://doaj.org/article/a8613f24f95b4dc89c0e4e40b8d220bb2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6374/11/11/440https://doaj.org/toc/2079-6374Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> (FAPbI<sub>3</sub>) PNPs in silica protective layer at room temperature (approximately 26 °C) employing (3-aminopropyl) triethoxysilane (APTES). The resulting perovskite nanocomposite (PNCs) achieved a high photoluminescence (PL) quantum yield of 58.0% and good stability under atmospheric moisture conditions. Moreover, the PNCs showed high PL intensity over 1 month of storage (approximately 26 °C) and more than 380 min of PNCs solutions in DI water. The studied near-infrared (NIR) light-emitting diode (LED) combined a NIR-emitting PNCs coating and a blue InGaN-based chip that exhibited a 788 nm electroluminescence spectrum of NIR-LEDs under 2.6 V. This may be a powerful tool to track of muscle and disabled patients in the detection of a blood vessel.Lung-Chien ChenLi-Wei ChaoChen-Yu XuChih-Hung HsuYi-Ting LeeZi-Min XuChun-Cheng LinZong-Liang TsengMDPI AGarticleperovskitenanocrystalsAPTESCH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>FAPbI<sub>3</sub>NIRBiotechnologyTP248.13-248.65ENBiosensors, Vol 11, Iss 440, p 440 (2021)
institution DOAJ
collection DOAJ
language EN
topic perovskite
nanocrystals
APTES
CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>
FAPbI<sub>3</sub>
NIR
Biotechnology
TP248.13-248.65
spellingShingle perovskite
nanocrystals
APTES
CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>
FAPbI<sub>3</sub>
NIR
Biotechnology
TP248.13-248.65
Lung-Chien Chen
Li-Wei Chao
Chen-Yu Xu
Chih-Hung Hsu
Yi-Ting Lee
Zi-Min Xu
Chun-Cheng Lin
Zong-Liang Tseng
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
description Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> (FAPbI<sub>3</sub>) PNPs in silica protective layer at room temperature (approximately 26 °C) employing (3-aminopropyl) triethoxysilane (APTES). The resulting perovskite nanocomposite (PNCs) achieved a high photoluminescence (PL) quantum yield of 58.0% and good stability under atmospheric moisture conditions. Moreover, the PNCs showed high PL intensity over 1 month of storage (approximately 26 °C) and more than 380 min of PNCs solutions in DI water. The studied near-infrared (NIR) light-emitting diode (LED) combined a NIR-emitting PNCs coating and a blue InGaN-based chip that exhibited a 788 nm electroluminescence spectrum of NIR-LEDs under 2.6 V. This may be a powerful tool to track of muscle and disabled patients in the detection of a blood vessel.
format article
author Lung-Chien Chen
Li-Wei Chao
Chen-Yu Xu
Chih-Hung Hsu
Yi-Ting Lee
Zi-Min Xu
Chun-Cheng Lin
Zong-Liang Tseng
author_facet Lung-Chien Chen
Li-Wei Chao
Chen-Yu Xu
Chih-Hung Hsu
Yi-Ting Lee
Zi-Min Xu
Chun-Cheng Lin
Zong-Liang Tseng
author_sort Lung-Chien Chen
title Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
title_short Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
title_full Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
title_fullStr Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
title_full_unstemmed Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
title_sort room-temperature synthesis of air-stable near-infrared emission in fapbi<sub>3</sub> nanoparticles embedded in silica
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/a8613f24f95b4dc89c0e4e40b8d220bb
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