Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica
Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>...
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2021
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oai:doaj.org-article:a8613f24f95b4dc89c0e4e40b8d220bb2021-11-25T16:55:24ZRoom-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica10.3390/bios111104402079-6374https://doaj.org/article/a8613f24f95b4dc89c0e4e40b8d220bb2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6374/11/11/440https://doaj.org/toc/2079-6374Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> (FAPbI<sub>3</sub>) PNPs in silica protective layer at room temperature (approximately 26 °C) employing (3-aminopropyl) triethoxysilane (APTES). The resulting perovskite nanocomposite (PNCs) achieved a high photoluminescence (PL) quantum yield of 58.0% and good stability under atmospheric moisture conditions. Moreover, the PNCs showed high PL intensity over 1 month of storage (approximately 26 °C) and more than 380 min of PNCs solutions in DI water. The studied near-infrared (NIR) light-emitting diode (LED) combined a NIR-emitting PNCs coating and a blue InGaN-based chip that exhibited a 788 nm electroluminescence spectrum of NIR-LEDs under 2.6 V. This may be a powerful tool to track of muscle and disabled patients in the detection of a blood vessel.Lung-Chien ChenLi-Wei ChaoChen-Yu XuChih-Hung HsuYi-Ting LeeZi-Min XuChun-Cheng LinZong-Liang TsengMDPI AGarticleperovskitenanocrystalsAPTESCH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub>FAPbI<sub>3</sub>NIRBiotechnologyTP248.13-248.65ENBiosensors, Vol 11, Iss 440, p 440 (2021) |
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DOAJ |
language |
EN |
topic |
perovskite nanocrystals APTES CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> FAPbI<sub>3</sub> NIR Biotechnology TP248.13-248.65 |
spellingShingle |
perovskite nanocrystals APTES CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> FAPbI<sub>3</sub> NIR Biotechnology TP248.13-248.65 Lung-Chien Chen Li-Wei Chao Chen-Yu Xu Chih-Hung Hsu Yi-Ting Lee Zi-Min Xu Chun-Cheng Lin Zong-Liang Tseng Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
description |
Hybrid organic−inorganic and all-inorganic metal halide perovskite nanoparticles (PNPs) have shown their excellent characteristics for optoelectronic applications. We report an atmospheric process to embed formamidinium CH(NH<sub>2</sub>)<sub>2</sub>PbI<sub>3</sub> (FAPbI<sub>3</sub>) PNPs in silica protective layer at room temperature (approximately 26 °C) employing (3-aminopropyl) triethoxysilane (APTES). The resulting perovskite nanocomposite (PNCs) achieved a high photoluminescence (PL) quantum yield of 58.0% and good stability under atmospheric moisture conditions. Moreover, the PNCs showed high PL intensity over 1 month of storage (approximately 26 °C) and more than 380 min of PNCs solutions in DI water. The studied near-infrared (NIR) light-emitting diode (LED) combined a NIR-emitting PNCs coating and a blue InGaN-based chip that exhibited a 788 nm electroluminescence spectrum of NIR-LEDs under 2.6 V. This may be a powerful tool to track of muscle and disabled patients in the detection of a blood vessel. |
format |
article |
author |
Lung-Chien Chen Li-Wei Chao Chen-Yu Xu Chih-Hung Hsu Yi-Ting Lee Zi-Min Xu Chun-Cheng Lin Zong-Liang Tseng |
author_facet |
Lung-Chien Chen Li-Wei Chao Chen-Yu Xu Chih-Hung Hsu Yi-Ting Lee Zi-Min Xu Chun-Cheng Lin Zong-Liang Tseng |
author_sort |
Lung-Chien Chen |
title |
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
title_short |
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
title_full |
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
title_fullStr |
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
title_full_unstemmed |
Room-Temperature Synthesis of Air-Stable Near-Infrared Emission in FAPbI<sub>3</sub> Nanoparticles Embedded in Silica |
title_sort |
room-temperature synthesis of air-stable near-infrared emission in fapbi<sub>3</sub> nanoparticles embedded in silica |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/a8613f24f95b4dc89c0e4e40b8d220bb |
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