Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions

Despite the burgeoning field of uranium-ligand multiple bond chemistry, analogous thorium compounds remain scarce. Here, the authors synthesize and characterize a series of thorium complexes with multiple bonds to phosphorus, and probe their 5f versus 6d orbital bonding character.

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Autores principales:	Elizabeth P. Wildman, Gábor Balázs, Ashley J. Wooles, Manfred Scheer, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/a8c04fbc074b48debf57a62235732ee3
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spelling	oai:doaj.org-article:a8c04fbc074b48debf57a62235732ee32021-12-02T14:38:57ZThorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions10.1038/ncomms128842041-1723https://doaj.org/article/a8c04fbc074b48debf57a62235732ee32016-09-01T00:00:00Zhttps://doi.org/10.1038/ncomms12884https://doaj.org/toc/2041-1723Despite the burgeoning field of uranium-ligand multiple bond chemistry, analogous thorium compounds remain scarce. Here, the authors synthesize and characterize a series of thorium complexes with multiple bonds to phosphorus, and probe their 5f versus 6d orbital bonding character.Elizabeth P. WildmanGábor BalázsAshley J. WoolesManfred ScheerStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
description	Despite the burgeoning field of uranium-ligand multiple bond chemistry, analogous thorium compounds remain scarce. Here, the authors synthesize and characterize a series of thorium complexes with multiple bonds to phosphorus, and probe their 5f versus 6d orbital bonding character.
format	article
author	Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle
author_facet	Elizabeth P. Wildman Gábor Balázs Ashley J. Wooles Manfred Scheer Stephen T. Liddle
author_sort	Elizabeth P. Wildman
title	Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
title_short	Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
title_full	Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
title_fullStr	Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
title_full_unstemmed	Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
title_sort	thorium–phosphorus triamidoamine complexes containing th–p single- and multiple-bond interactions
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/a8c04fbc074b48debf57a62235732ee3
work_keys_str_mv	AT elizabethpwildman thoriumphosphorustriamidoaminecomplexescontainingthpsingleandmultiplebondinteractions AT gaborbalazs thoriumphosphorustriamidoaminecomplexescontainingthpsingleandmultiplebondinteractions AT ashleyjwooles thoriumphosphorustriamidoaminecomplexescontainingthpsingleandmultiplebondinteractions AT manfredscheer thoriumphosphorustriamidoaminecomplexescontainingthpsingleandmultiplebondinteractions AT stephentliddle thoriumphosphorustriamidoaminecomplexescontainingthpsingleandmultiplebondinteractions
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Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions

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