Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them withi...
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Nature Portfolio
2017
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oai:doaj.org-article:a9a7ef7883eb49e2a96f2fcdf29a96cb2021-12-02T14:41:10ZExact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix10.1038/s41467-017-00605-52041-1723https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00605-5https://doaj.org/toc/2041-1723The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules.Sho MatsunoMasahiro YamashinaYoshihisa SeiMunetaka AkitaAkiyoshi KuzumeKimihisa YamamotoMichito YoshizawaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017) |
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Science Q Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
description |
The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules. |
format |
article |
author |
Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa |
author_facet |
Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa |
author_sort |
Sho Matsuno |
title |
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
title_short |
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
title_full |
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
title_fullStr |
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
title_full_unstemmed |
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
title_sort |
exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb |
work_keys_str_mv |
AT shomatsuno exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT masahiroyamashina exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT yoshihisasei exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT munetakaakita exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT akiyoshikuzume exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT kimihisayamamoto exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix AT michitoyoshizawa exactmassanalysisofsulfurclustersuponencapsulationbyapolyaromaticcapsularmatrix |
_version_ |
1718390011420737536 |