Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix

The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them withi...

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Autores principales: Sho Matsuno, Masahiro Yamashina, Yoshihisa Sei, Munetaka Akita, Akiyoshi Kuzume, Kimihisa Yamamoto, Michito Yoshizawa
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb
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spelling oai:doaj.org-article:a9a7ef7883eb49e2a96f2fcdf29a96cb2021-12-02T14:41:10ZExact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix10.1038/s41467-017-00605-52041-1723https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00605-5https://doaj.org/toc/2041-1723The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules.Sho MatsunoMasahiro YamashinaYoshihisa SeiMunetaka AkitaAkiyoshi KuzumeKimihisa YamamotoMichito YoshizawaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Sho Matsuno
Masahiro Yamashina
Yoshihisa Sei
Munetaka Akita
Akiyoshi Kuzume
Kimihisa Yamamoto
Michito Yoshizawa
Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
description The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules.
format article
author Sho Matsuno
Masahiro Yamashina
Yoshihisa Sei
Munetaka Akita
Akiyoshi Kuzume
Kimihisa Yamamoto
Michito Yoshizawa
author_facet Sho Matsuno
Masahiro Yamashina
Yoshihisa Sei
Munetaka Akita
Akiyoshi Kuzume
Kimihisa Yamamoto
Michito Yoshizawa
author_sort Sho Matsuno
title Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_short Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_full Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_fullStr Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_full_unstemmed Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_sort exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb
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