Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix

The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them withi...

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Main Authors:	Sho Matsuno, Masahiro Yamashina, Yoshihisa Sei, Munetaka Akita, Akiyoshi Kuzume, Kimihisa Yamamoto, Michito Yoshizawa
Format:	article
Language:	EN
Published:	Nature Portfolio 2017
Subjects:	Science Q
Online Access:	https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb
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spelling	oai:doaj.org-article:a9a7ef7883eb49e2a96f2fcdf29a96cb2021-12-02T14:41:10ZExact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix10.1038/s41467-017-00605-52041-1723https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00605-5https://doaj.org/toc/2041-1723The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules.Sho MatsunoMasahiro YamashinaYoshihisa SeiMunetaka AkitaAkiyoshi KuzumeKimihisa YamamotoMichito YoshizawaNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
description	The structures of inorganic clusters are commonly characterized by mass spectrometry (MS), but neutral sulfur clusters heavily fragment under MS conditions, preventing their exact mass determination. Here, the authors successfully perform MS on labile cyclic sulfur clusters by stabilizing them within ionic supramolecular capsules.
format	article
author	Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa
author_facet	Sho Matsuno Masahiro Yamashina Yoshihisa Sei Munetaka Akita Akiyoshi Kuzume Kimihisa Yamamoto Michito Yoshizawa
author_sort	Sho Matsuno
title	Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_short	Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_full	Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_fullStr	Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_full_unstemmed	Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
title_sort	exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/a9a7ef7883eb49e2a96f2fcdf29a96cb
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Exact mass analysis of sulfur clusters upon encapsulation by a polyaromatic capsular matrix

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