A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core

A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core

A new [Mn6O2(O2CCMe3)10(HO2CCMe3)(EtOH)3]∙EtOH hexanuclear mixed-valent coordination compound with a {Mn6O2} core has been synthesized and characterized by single-crystal X-ray diffraction analysis. The central mixed-valence [MnII4MnIII2(M4-O2)]10+ core consists of six Mn centers, two MnIII and four...

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Autor principal: Darii, Mariana
Formato: article
Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2019
Materias:
Physics
QC1-999
Electronics
TK7800-8360
Acceso en línea:https://doaj.org/article/aa3eb503ab8d4ec0add562873126f4a7
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spelling oai:doaj.org-article:aa3eb503ab8d4ec0add562873126f4a72021-11-21T11:55:49ZA hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core539.2+548.4+5442537-63651810-648Xhttps://doaj.org/article/aa3eb503ab8d4ec0add562873126f4a72019-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2019/article/98831https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A new [Mn6O2(O2CCMe3)10(HO2CCMe3)(EtOH)3]∙EtOH hexanuclear mixed-valent coordination compound with a {Mn6O2} core has been synthesized and characterized by single-crystal X-ray diffraction analysis. The central mixed-valence [MnII4MnIII2(M4-O2)]10+ core consists of six Mn centers, two MnIII and four MnII ions, arranged as two edge-sharing flattened Mn4 tetrahedra, with a M4-O2- ion in the center of each tetrahedron. Peripheral ligation is provided by pivalate and ethanol groupsDarii, MarianaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 18, Iss 1-4, Pp 59-64 (2019)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Darii, Mariana
A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
description A new [Mn6O2(O2CCMe3)10(HO2CCMe3)(EtOH)3]∙EtOH hexanuclear mixed-valent coordination compound with a {Mn6O2} core has been synthesized and characterized by single-crystal X-ray diffraction analysis. The central mixed-valence [MnII4MnIII2(M4-O2)]10+ core consists of six Mn centers, two MnIII and four MnII ions, arranged as two edge-sharing flattened Mn4 tetrahedra, with a M4-O2- ion in the center of each tetrahedron. Peripheral ligation is provided by pivalate and ethanol groups
format article
author Darii, Mariana
author_facet Darii, Mariana
author_sort Darii, Mariana
title A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
title_short A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
title_full A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
title_fullStr A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
title_full_unstemmed A hexanuclear Mn(II, III) pivalate cluster with a {Mn6O2} core
title_sort hexanuclear mn(ii, iii) pivalate cluster with a {mn6o2} core
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2019
url https://doaj.org/article/aa3eb503ab8d4ec0add562873126f4a7
work_keys_str_mv AT dariimariana ahexanuclearmniiiiipivalateclusterwithamn6o2core
AT dariimariana hexanuclearmniiiiipivalateclusterwithamn6o2core
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