Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating

Advanced high-strength steels protected by zinc coatings have contributed to a reduction in CO<sub>2</sub> emissions in the automotive industry. However, the liquid metal embrittlement (LME) of the Fe/Zn couple induced by simultaneously acting stresses and high temperatures during resist...

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Autores principales: Vojtech Kucera, Zuzana Zofkova, Christopher DiGiovanni, Liu He, Dalibor Vojtěch
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/aa9775966d7645ee8c8c30e6019905b6
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spelling oai:doaj.org-article:aa9775966d7645ee8c8c30e6019905b62021-11-25T18:22:09ZInvestigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating10.3390/met111118132075-4701https://doaj.org/article/aa9775966d7645ee8c8c30e6019905b62021-11-01T00:00:00Zhttps://www.mdpi.com/2075-4701/11/11/1813https://doaj.org/toc/2075-4701Advanced high-strength steels protected by zinc coatings have contributed to a reduction in CO<sub>2</sub> emissions in the automotive industry. However, the liquid metal embrittlement (LME) of the Fe/Zn couple induced by simultaneously acting stresses and high temperatures during resistance spot welding could be the cause of unexpected failure. We investigated the possible risk of LME in spot-welded martensitic steel with Zn jet vapor-deposited coating and its influence on weld strength. The weld nugget cross-sections were analyzed (optical microscopy, SEM-EDS), and their tensile shear strengths were compared with their uncoated counterparts. LME cracks were observed in all samples meeting the process window (6, 6.5, 7 kA) located at the edge of the sheet/electrode indentation area. The frequency and length of cracks increased with current, and the occurrence of Zn within cracks indicated the LME mechanism. The shear tests showed the Zn-coated sample underwent a decrease in tensile shear strength that was most evident at a welding current of 7 kA (13.2%). However, LME was excluded as a cause of lower strength. The decrease was attributed to the smaller nugget diameter and the thin slit of Zn coating remaining in the weld notch.Vojtech KuceraZuzana ZofkovaChristopher DiGiovanniLiu HeDalibor VojtěchMDPI AGarticleliquid metal embrittlementresistance spot weldingjet vapor depositionmartensitic steelMining engineering. MetallurgyTN1-997ENMetals, Vol 11, Iss 1813, p 1813 (2021)
institution DOAJ
collection DOAJ
language EN
topic liquid metal embrittlement
resistance spot welding
jet vapor deposition
martensitic steel
Mining engineering. Metallurgy
TN1-997
spellingShingle liquid metal embrittlement
resistance spot welding
jet vapor deposition
martensitic steel
Mining engineering. Metallurgy
TN1-997
Vojtech Kucera
Zuzana Zofkova
Christopher DiGiovanni
Liu He
Dalibor Vojtěch
Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
description Advanced high-strength steels protected by zinc coatings have contributed to a reduction in CO<sub>2</sub> emissions in the automotive industry. However, the liquid metal embrittlement (LME) of the Fe/Zn couple induced by simultaneously acting stresses and high temperatures during resistance spot welding could be the cause of unexpected failure. We investigated the possible risk of LME in spot-welded martensitic steel with Zn jet vapor-deposited coating and its influence on weld strength. The weld nugget cross-sections were analyzed (optical microscopy, SEM-EDS), and their tensile shear strengths were compared with their uncoated counterparts. LME cracks were observed in all samples meeting the process window (6, 6.5, 7 kA) located at the edge of the sheet/electrode indentation area. The frequency and length of cracks increased with current, and the occurrence of Zn within cracks indicated the LME mechanism. The shear tests showed the Zn-coated sample underwent a decrease in tensile shear strength that was most evident at a welding current of 7 kA (13.2%). However, LME was excluded as a cause of lower strength. The decrease was attributed to the smaller nugget diameter and the thin slit of Zn coating remaining in the weld notch.
format article
author Vojtech Kucera
Zuzana Zofkova
Christopher DiGiovanni
Liu He
Dalibor Vojtěch
author_facet Vojtech Kucera
Zuzana Zofkova
Christopher DiGiovanni
Liu He
Dalibor Vojtěch
author_sort Vojtech Kucera
title Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
title_short Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
title_full Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
title_fullStr Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
title_full_unstemmed Investigation of Liquid Metal Embrittlement during Resistance Spot Welding of Martensitic Steel with Zn Jet Vapor-Deposited Coating
title_sort investigation of liquid metal embrittlement during resistance spot welding of martensitic steel with zn jet vapor-deposited coating
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/aa9775966d7645ee8c8c30e6019905b6
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