Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor

Abstract The present study investigates the fabrication of hierarchical 3D nanostructures with multi-component metal oxides in the presence of highly-porous graphene and characterized for its applications in high-performance supercapacitors. A hierarchical flowers like 3D nanostructure of Co3O4 @MnO...

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Autores principales: Sivalingam Ramesh, K. Karuppasamy, Hyun-Seok Kim, Heung Soo Kim, Joo-Hyung Kim
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Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/abbb112be2904dcbb08c716257a41501
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spelling oai:doaj.org-article:abbb112be2904dcbb08c716257a415012021-12-02T15:08:22ZHierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor10.1038/s41598-018-34905-72045-2322https://doaj.org/article/abbb112be2904dcbb08c716257a415012018-11-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-34905-7https://doaj.org/toc/2045-2322Abstract The present study investigates the fabrication of hierarchical 3D nanostructures with multi-component metal oxides in the presence of highly-porous graphene and characterized for its applications in high-performance supercapacitors. A hierarchical flowers like 3D nanostructure of Co3O4 @MnO2 on nitrogen-doped graphene oxide (NGO) hybrid composite was synthesized by thermal reduction process at 650 °C in the presence of ammonia and urea. The synthesized Co3O4@MnO2/NGO hybrid composites were studied via Raman, XRD, X-ray XPS, FE-SEM, FE-SEM with EDX, FE-TEM and BET analyses. The electrochemical analysis of Co3O4@MnO2/NGO hybrid composite electrode was investigated using cyclic voltammetry, chronopotentiometry and electrochemical impedance measurements. The hybrid composite electrode showed significant specific capacitance results of up to 347 F/g at 0.5 A/g and a corresponding energy density of 34.83 Wh kg−1 with better rate performance and excellent long-term cycling stability were achieved for 10,000 cycles. The obtained electrochemical results paved a way to utilize Co3O4@MnO2/NGO composite electrode as a promising electrode material in high performance supercapacitors.Sivalingam RameshK. KaruppasamyHyun-Seok KimHeung Soo KimJoo-Hyung KimNature PortfolioarticleHybrid CompositesGraphene Oxide (GO)High Performance SupercapacitorsThermal Reduction ProcessHierarchical FlowMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-11 (2018)
institution DOAJ
collection DOAJ
language EN
topic Hybrid Composites
Graphene Oxide (GO)
High Performance Supercapacitors
Thermal Reduction Process
Hierarchical Flow
Medicine
R
Science
Q
spellingShingle Hybrid Composites
Graphene Oxide (GO)
High Performance Supercapacitors
Thermal Reduction Process
Hierarchical Flow
Medicine
R
Science
Q
Sivalingam Ramesh
K. Karuppasamy
Hyun-Seok Kim
Heung Soo Kim
Joo-Hyung Kim
Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
description Abstract The present study investigates the fabrication of hierarchical 3D nanostructures with multi-component metal oxides in the presence of highly-porous graphene and characterized for its applications in high-performance supercapacitors. A hierarchical flowers like 3D nanostructure of Co3O4 @MnO2 on nitrogen-doped graphene oxide (NGO) hybrid composite was synthesized by thermal reduction process at 650 °C in the presence of ammonia and urea. The synthesized Co3O4@MnO2/NGO hybrid composites were studied via Raman, XRD, X-ray XPS, FE-SEM, FE-SEM with EDX, FE-TEM and BET analyses. The electrochemical analysis of Co3O4@MnO2/NGO hybrid composite electrode was investigated using cyclic voltammetry, chronopotentiometry and electrochemical impedance measurements. The hybrid composite electrode showed significant specific capacitance results of up to 347 F/g at 0.5 A/g and a corresponding energy density of 34.83 Wh kg−1 with better rate performance and excellent long-term cycling stability were achieved for 10,000 cycles. The obtained electrochemical results paved a way to utilize Co3O4@MnO2/NGO composite electrode as a promising electrode material in high performance supercapacitors.
format article
author Sivalingam Ramesh
K. Karuppasamy
Hyun-Seok Kim
Heung Soo Kim
Joo-Hyung Kim
author_facet Sivalingam Ramesh
K. Karuppasamy
Hyun-Seok Kim
Heung Soo Kim
Joo-Hyung Kim
author_sort Sivalingam Ramesh
title Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
title_short Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
title_full Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
title_fullStr Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
title_full_unstemmed Hierarchical Flowerlike 3D nanostructure of Co3O4@MnO2/N-doped Graphene oxide (NGO) hybrid composite for a high-performance supercapacitor
title_sort hierarchical flowerlike 3d nanostructure of co3o4@mno2/n-doped graphene oxide (ngo) hybrid composite for a high-performance supercapacitor
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/abbb112be2904dcbb08c716257a41501
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AT kkaruppasamy hierarchicalflowerlike3dnanostructureofco3o4mno2ndopedgrapheneoxidengohybridcompositeforahighperformancesupercapacitor
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