Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology

Co-torrefaction of microalgae and lignocellulosic biomass was evaluated as a method to process microalgae sludge produced from various effluents and to obtain biochars with suitable properties for energy or material valorization. The influence of four independent variables on biochar yield and prope...

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Autores principales: Catarina Viegas, Catarina Nobre, Ricardo Correia, Luísa Gouveia, Margarida Gonçalves
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:abd70bec21cd443f807333cbe7bbdffa2021-11-11T16:03:23ZOptimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology10.3390/en142173301996-1073https://doaj.org/article/abd70bec21cd443f807333cbe7bbdffa2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1073/14/21/7330https://doaj.org/toc/1996-1073Co-torrefaction of microalgae and lignocellulosic biomass was evaluated as a method to process microalgae sludge produced from various effluents and to obtain biochars with suitable properties for energy or material valorization. The influence of four independent variables on biochar yield and properties was evaluated by a set of experiments defined by response surface methodology (RSM). The biochars were characterized for proximate and ultimate composition, HHV, and methylene blue adsorption capacity. HHV of the biochars was positively correlated with carbonization temperature, residence time, and lignocellulosic biomass content in the feed. Co-torrefaction conditions that led to a higher yield of biochar (76.5%) with good calorific value (17.4 MJ Kg<sup>−1</sup>) were 250 °C, 60 min of residence time, 5% feed moisture, and 50% lignocellulosic biomass. The energy efficiency of the process was higher for lower temperatures (92.6%) but decreased abruptly with the increase of the moisture content of the feed mixture (16.9 to 57.3% for 70% moisture). Biochars produced using algal biomass grown in contaminated effluents presented high ash content and low calorific value. Dye removal efficiency by the produced biochars was tested, reaching 95% methylene blue adsorption capacity for the biochars produced with the least severe torrefaction conditions.Catarina ViegasCatarina NobreRicardo CorreiaLuísa GouveiaMargarida GonçalvesMDPI AGarticle<i>Chlorella vulgaris</i>lignocellulosic biomassbiochartorrefactioncarbonizationRSMTechnologyTENEnergies, Vol 14, Iss 7330, p 7330 (2021)
institution DOAJ
collection DOAJ
language EN
topic <i>Chlorella vulgaris</i>
lignocellulosic biomass
biochar
torrefaction
carbonization
RSM
Technology
T
spellingShingle <i>Chlorella vulgaris</i>
lignocellulosic biomass
biochar
torrefaction
carbonization
RSM
Technology
T
Catarina Viegas
Catarina Nobre
Ricardo Correia
Luísa Gouveia
Margarida Gonçalves
Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
description Co-torrefaction of microalgae and lignocellulosic biomass was evaluated as a method to process microalgae sludge produced from various effluents and to obtain biochars with suitable properties for energy or material valorization. The influence of four independent variables on biochar yield and properties was evaluated by a set of experiments defined by response surface methodology (RSM). The biochars were characterized for proximate and ultimate composition, HHV, and methylene blue adsorption capacity. HHV of the biochars was positively correlated with carbonization temperature, residence time, and lignocellulosic biomass content in the feed. Co-torrefaction conditions that led to a higher yield of biochar (76.5%) with good calorific value (17.4 MJ Kg<sup>−1</sup>) were 250 °C, 60 min of residence time, 5% feed moisture, and 50% lignocellulosic biomass. The energy efficiency of the process was higher for lower temperatures (92.6%) but decreased abruptly with the increase of the moisture content of the feed mixture (16.9 to 57.3% for 70% moisture). Biochars produced using algal biomass grown in contaminated effluents presented high ash content and low calorific value. Dye removal efficiency by the produced biochars was tested, reaching 95% methylene blue adsorption capacity for the biochars produced with the least severe torrefaction conditions.
format article
author Catarina Viegas
Catarina Nobre
Ricardo Correia
Luísa Gouveia
Margarida Gonçalves
author_facet Catarina Viegas
Catarina Nobre
Ricardo Correia
Luísa Gouveia
Margarida Gonçalves
author_sort Catarina Viegas
title Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
title_short Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
title_full Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
title_fullStr Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
title_full_unstemmed Optimization of Biochar Production by Co-Torrefaction of Microalgae and Lignocellulosic Biomass Using Response Surface Methodology
title_sort optimization of biochar production by co-torrefaction of microalgae and lignocellulosic biomass using response surface methodology
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/abd70bec21cd443f807333cbe7bbdffa
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AT catarinanobre optimizationofbiocharproductionbycotorrefactionofmicroalgaeandlignocellulosicbiomassusingresponsesurfacemethodology
AT ricardocorreia optimizationofbiocharproductionbycotorrefactionofmicroalgaeandlignocellulosicbiomassusingresponsesurfacemethodology
AT luisagouveia optimizationofbiocharproductionbycotorrefactionofmicroalgaeandlignocellulosicbiomassusingresponsesurfacemethodology
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