Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets

Rhenium(IV) complexes are magnetically anisotropic although the origin of this anisotropy is poorly explored compared to 3dtransition metals and lanthanides. Here, the authors computationally examine the effects of ligand donor ability and structural distortion on magnetic anisotropy for a series of...

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Autores principales:	Saurabh Kumar Singh, Gopalan Rajaraman
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ac2732a2fb024a69b7b0dae4dfc5ddb4
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spelling	oai:doaj.org-article:ac2732a2fb024a69b7b0dae4dfc5ddb42021-12-02T17:31:19ZDeciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets10.1038/ncomms106692041-1723https://doaj.org/article/ac2732a2fb024a69b7b0dae4dfc5ddb42016-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms10669https://doaj.org/toc/2041-1723Rhenium(IV) complexes are magnetically anisotropic although the origin of this anisotropy is poorly explored compared to 3dtransition metals and lanthanides. Here, the authors computationally examine the effects of ligand donor ability and structural distortion on magnetic anisotropy for a series of rhenium(IV) complexes.Saurabh Kumar SinghGopalan RajaramanNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-8 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Saurabh Kumar Singh Gopalan Rajaraman Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
description	Rhenium(IV) complexes are magnetically anisotropic although the origin of this anisotropy is poorly explored compared to 3dtransition metals and lanthanides. Here, the authors computationally examine the effects of ligand donor ability and structural distortion on magnetic anisotropy for a series of rhenium(IV) complexes.
format	article
author	Saurabh Kumar Singh Gopalan Rajaraman
author_facet	Saurabh Kumar Singh Gopalan Rajaraman
author_sort	Saurabh Kumar Singh
title	Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
title_short	Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
title_full	Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
title_fullStr	Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
title_full_unstemmed	Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets
title_sort	deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in rhenium(iv) single-molecule magnets
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/ac2732a2fb024a69b7b0dae4dfc5ddb4
work_keys_str_mv	AT saurabhkumarsingh decipheringtheoriginofgiantmagneticanisotropyandfastquantumtunnellinginrheniumivsinglemoleculemagnets AT gopalanrajaraman decipheringtheoriginofgiantmagneticanisotropyandfastquantumtunnellinginrheniumivsinglemoleculemagnets
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Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium(IV) single-molecule magnets

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