A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization

The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.

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Detalles Bibliográficos
Autores principales: Yusuke Hibi, Makoto Ouchi, Mitsuo Sawamoto
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/adb05ec269384e26887e8eee9d8579f9
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Descripción
Sumario:The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.