A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.
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Nature Portfolio
2016
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oai:doaj.org-article:adb05ec269384e26887e8eee9d8579f92021-12-02T14:38:34ZA strategy for sequence control in vinyl polymers via iterative controlled radical cyclization10.1038/ncomms110642041-1723https://doaj.org/article/adb05ec269384e26887e8eee9d8579f92016-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms11064https://doaj.org/toc/2041-1723The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.Yusuke HibiMakoto OuchiMitsuo SawamotoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-9 (2016) |
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Science Q Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
description |
The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers. |
format |
article |
author |
Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto |
author_facet |
Yusuke Hibi Makoto Ouchi Mitsuo Sawamoto |
author_sort |
Yusuke Hibi |
title |
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
title_short |
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
title_full |
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
title_fullStr |
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
title_full_unstemmed |
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
title_sort |
strategy for sequence control in vinyl polymers via iterative controlled radical cyclization |
publisher |
Nature Portfolio |
publishDate |
2016 |
url |
https://doaj.org/article/adb05ec269384e26887e8eee9d8579f9 |
work_keys_str_mv |
AT yusukehibi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization AT makotoouchi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization AT mitsuosawamoto astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization AT yusukehibi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization AT makotoouchi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization AT mitsuosawamoto strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization |
_version_ |
1718390971414085632 |