A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization

The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.

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Autores principales: Yusuke Hibi, Makoto Ouchi, Mitsuo Sawamoto
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/adb05ec269384e26887e8eee9d8579f9
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spelling oai:doaj.org-article:adb05ec269384e26887e8eee9d8579f92021-12-02T14:38:34ZA strategy for sequence control in vinyl polymers via iterative controlled radical cyclization10.1038/ncomms110642041-1723https://doaj.org/article/adb05ec269384e26887e8eee9d8579f92016-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms11064https://doaj.org/toc/2041-1723The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.Yusuke HibiMakoto OuchiMitsuo SawamotoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-9 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
description The ultimate control in polymer synthesis, precise monomer sequencing, is a highly sought after but complex problem. Here, the authors employ a repetitive and iterative intramolecular cyclization reaction, via a radical intermediate, to generate sequence-controlled vinyl oligomers.
format article
author Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
author_facet Yusuke Hibi
Makoto Ouchi
Mitsuo Sawamoto
author_sort Yusuke Hibi
title A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_short A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_full A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_fullStr A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_full_unstemmed A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
title_sort strategy for sequence control in vinyl polymers via iterative controlled radical cyclization
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/adb05ec269384e26887e8eee9d8579f9
work_keys_str_mv AT yusukehibi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT makotoouchi astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT mitsuosawamoto astrategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT yusukehibi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT makotoouchi strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
AT mitsuosawamoto strategyforsequencecontrolinvinylpolymersviaiterativecontrolledradicalcyclization
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