Charge transfer drives anomalous phase transition in ceria

Charge transfer drives anomalous phase transition in ceria

Nanosized ceria has conventionally been thought to have a cubic fluorite structure. Here, the authors use a combination of experiments and simulations to show that oxygen vacancies in ceria promote a charge-transfer induced phase transition from tetragonal to cubic.

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Autores principales: He Zhu, Chao Yang, Qiang Li, Yang Ren, Joerg C. Neuefeind, Lin Gu, Huibiao Liu, Longlong Fan, Jun Chen, Jinxia Deng, Na Wang, Jiawang Hong, Xianran Xing
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/adcd860d72c0421c8136473f6686fe3d
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spelling oai:doaj.org-article:adcd860d72c0421c8136473f6686fe3d2021-12-02T17:33:03ZCharge transfer drives anomalous phase transition in ceria10.1038/s41467-018-07526-x2041-1723https://doaj.org/article/adcd860d72c0421c8136473f6686fe3d2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07526-xhttps://doaj.org/toc/2041-1723Nanosized ceria has conventionally been thought to have a cubic fluorite structure. Here, the authors use a combination of experiments and simulations to show that oxygen vacancies in ceria promote a charge-transfer induced phase transition from tetragonal to cubic.He ZhuChao YangQiang LiYang RenJoerg C. NeuefeindLin GuHuibiao LiuLonglong FanJun ChenJinxia DengNa WangJiawang HongXianran XingNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
He Zhu
Chao Yang
Qiang Li
Yang Ren
Joerg C. Neuefeind
Lin Gu
Huibiao Liu
Longlong Fan
Jun Chen
Jinxia Deng
Na Wang
Jiawang Hong
Xianran Xing
Charge transfer drives anomalous phase transition in ceria
description Nanosized ceria has conventionally been thought to have a cubic fluorite structure. Here, the authors use a combination of experiments and simulations to show that oxygen vacancies in ceria promote a charge-transfer induced phase transition from tetragonal to cubic.
format article
author He Zhu
Chao Yang
Qiang Li
Yang Ren
Joerg C. Neuefeind
Lin Gu
Huibiao Liu
Longlong Fan
Jun Chen
Jinxia Deng
Na Wang
Jiawang Hong
Xianran Xing
author_facet He Zhu
Chao Yang
Qiang Li
Yang Ren
Joerg C. Neuefeind
Lin Gu
Huibiao Liu
Longlong Fan
Jun Chen
Jinxia Deng
Na Wang
Jiawang Hong
Xianran Xing
author_sort He Zhu
title Charge transfer drives anomalous phase transition in ceria
title_short Charge transfer drives anomalous phase transition in ceria
title_full Charge transfer drives anomalous phase transition in ceria
title_fullStr Charge transfer drives anomalous phase transition in ceria
title_full_unstemmed Charge transfer drives anomalous phase transition in ceria
title_sort charge transfer drives anomalous phase transition in ceria
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/adcd860d72c0421c8136473f6686fe3d
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AT chaoyang chargetransferdrivesanomalousphasetransitioninceria
AT qiangli chargetransferdrivesanomalousphasetransitioninceria
AT yangren chargetransferdrivesanomalousphasetransitioninceria
AT joergcneuefeind chargetransferdrivesanomalousphasetransitioninceria
AT lingu chargetransferdrivesanomalousphasetransitioninceria
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AT jinxiadeng chargetransferdrivesanomalousphasetransitioninceria
AT nawang chargetransferdrivesanomalousphasetransitioninceria
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